{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T19:47:19Z","timestamp":1790279239836,"version":"4.1.0"},"reference-count":41,"publisher":"The Royal Society","issue":"2167","license":[{"start":{"date-parts":[[2020,2,3]],"date-time":"2020-02-03T00:00:00Z","timestamp":1580688000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/royalsociety.org\/journals\/ethics-policies\/data-sharing-mining\/"}],"content-domain":{"domain":["royalsocietypublishing.org"],"crossmark-restriction":true},"short-container-title":["Phil. Trans. R. Soc. A."],"published-print":{"date-parts":[[2020,3,20]]},"abstract":"<jats:p>\n            Here, a bioinspired strategy is used to prepare well-ordered nanotubular structures, as observed in animals and plants, such as gecko toe pads or corals. The nanotubes are obtained by templateless electropolymerization of thieno[3,4-\n            <jats:italic>b<\/jats:italic>\n            ]thiophene-based monomers with various aromatic groups in an organic solvent (dichloromethane). The most interesting and robust structures were obtained with carbazole and pyrene substituents to the base monomer structure, since these groups participate significantly in the polymerization and also have strong\n            <jats:italic>\u03c0<\/jats:italic>\n            -stacking interactions. The addition of water to electropolymerization solvent significantly impacted the formation of nanotubes, as it caused the release of a significant amount of H\n            <jats:sub>2<\/jats:sub>\n            and O\n            <jats:sub>2<\/jats:sub>\n            bubbles, depending on the electropolymerization method. Identifying templateless approaches to vary nanotubular structures is very interesting, as these materials are sought-after for applications in water harvesting systems.\n          <\/jats:p>\n          <jats:p>This article is part of the theme issue \u2018Bioinspired materials and surfaces for green science and technology (part 3)\u2019.<\/jats:p>","DOI":"10.1098\/rsta.2019.0450","type":"journal-article","created":{"date-parts":[[2020,2,3]],"date-time":"2020-02-03T08:05:21Z","timestamp":1580717121000},"page":"20190450","update-policy":"https:\/\/doi.org\/10.1098\/crossmark-policy","source":"Crossref","is-referenced-by-count":13,"title":["A bioinspired strategy for designing well-ordered nanotubular structures by templateless electropolymerization of thieno[3,4-\n            <i>b<\/i>\n            ]thiophene-based monomers"],"prefix":"10.1098","volume":"378","author":[{"given":"Imen","family":"Bousrih","sequence":"first","affiliation":[{"name":"Laboratory of Structural Organic Chemistry, Faculty of Sciences of Tunis, University of Tunis El Manar, 2092 Tunis, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mejda","family":"El Kateb","sequence":"additional","affiliation":[{"name":"Laboratory of Structural Organic Chemistry, Faculty of Sciences of Tunis, University of Tunis El Manar, 2092 Tunis, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6991-970X","authenticated-orcid":true,"given":"Caroline R.","family":"Szczepanski","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering and Materials Science, Michigan State University, East Lansing, MI, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohammed","family":"Beji","sequence":"additional","affiliation":[{"name":"Laboratory of Structural Organic Chemistry, Faculty of Sciences of Tunis, University of Tunis El Manar, 2092 Tunis, Tunisia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fr\u00e9d\u00e9ric","family":"Guittard","sequence":"additional","affiliation":[{"name":"Universit\u00e9 C\u00f4te d'Azur, NICE Lab, 06200 Nice, France"},{"name":"Department of Bioengineering, University of California Riverside, Riverside, CA, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0150-7412","authenticated-orcid":true,"given":"Thierry","family":"Darmanin","sequence":"additional","affiliation":[{"name":"Universit\u00e9 C\u00f4te d'Azur, NICE Lab, 06200 Nice, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"175","published-online":{"date-parts":[[2020,2,3]]},"reference":[{"key":"e_1_3_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00128"},{"key":"e_1_3_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA11298B"},{"key":"e_1_3_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/b923416k"},{"key":"e_1_3_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003314"},{"key":"e_1_3_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/la904510n"},{"key":"e_1_3_6_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9SM01167F"},{"key":"e_1_3_6_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2sm25443c"},{"key":"e_1_3_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201803890"},{"key":"e_1_3_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/nl034704t"},{"key":"e_1_3_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b12728"},{"key":"e_1_3_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2015.01.001"},{"key":"e_1_3_6_13_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-016-0125-1"},{"key":"e_1_3_6_14_2","first-page":"20071078","article-title":"The adhesion model considering capillarity for gecko attachment system","volume":"5","author":"Kim TW","year":"2007","journal-title":"J. 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