{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T15:11:43Z","timestamp":1778771503956,"version":"3.51.4"},"reference-count":57,"publisher":"The Royal Society","issue":"2318","license":[{"start":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T00:00:00Z","timestamp":1776297600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T00:00:00Z","timestamp":1776297600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,4,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Styrene epoxidation to afford its epoxides shows a promising approach for value-added chemicals construction. By virtue of Ni-modified AlOOH nanoflowers as starting materials, secondary adsorption and thermal treatment transform the composite into Co\/Cu coupled with NiO-modified Al2O3 nanoflowers. The results indicate that the Ni-modification improves the structural properties of AlOOH and regulates the morphology, while calcination treatment contributes to the surface area enlargement and hierarchical pore structure formation, which benefits the diffusion and accessibility of reactant molecules approaching reactive sites. The secondary introduced metal, including Cu\/Co, affords a well-dispersed state close to the in situ formed NiO over the Al2O3 nanoflowers. It was found that the Co-modified catalyst Al2O3(Ni)\u2013Cu exhibited the highest styrene conversion rate and styrene oxide selectivity compared to the Co-modified Al2O3(Ni)\u2013Co and Al2O3(Ni). In addition, Al2O3(Ni)\u2013Cu further showcases the great potential in the selective benzene oxidation to benzoquinone, in which benzene conversion reaches 60% at 10 h, and the benzoquinone selectivity was more than 90%, with near 1448 \u03bcmol yield. This finding indicates that copper and nickel species exert synergistic effects by electronic interactions between bimetals to influence the generation of final products, which provides valuable references for further research in related fields.<\/jats:p>\n                  <jats:p>This article is part of the theme issue \u2018Surfaces, interfaces and heterogeneous catalysis\u2019.<\/jats:p>","DOI":"10.1098\/rsta.2024.0467","type":"journal-article","created":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T08:09:41Z","timestamp":1776326981000},"source":"Crossref","is-referenced-by-count":1,"title":["Rational construction of secondary metal on to Ni-modified Al2O3 nanoflower to achieve synergetic catalytic epoxidation of styrene"],"prefix":"10.1098","volume":"384","author":[{"given":"Wanyu","family":"Zhang","sequence":"first","affiliation":[{"name":"Jiangsu University of Science and Technology 1 , , ,","place":["Zhenjiang, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hao","family":"Lu","sequence":"additional","affiliation":[{"name":"Jiangsu University of Science and Technology 1 , , ,","place":["Zhenjiang, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Danhong","family":"Shang","sequence":"additional","affiliation":[{"name":"Jiangsu University of Science and Technology 1 , , ,","place":["Zhenjiang, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xinwei","family":"Zhou","sequence":"additional","affiliation":[{"name":"Jiangsu University of Science and Technology 1 , , ,","place":["Zhenjiang, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qian","family":"Wang","sequence":"additional","affiliation":[{"name":"Yangzhou University 2 , , ,","place":["Yangzhou, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zengjing","family":"Guo","sequence":"additional","affiliation":[{"name":"Liao Cheng University 3 , , ,","place":["Liaocheng, Shandong, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yangping","family":"Zhang","sequence":"additional","affiliation":[{"name":"Jiangsu University of Science and Technology 1 , , ,","place":["Zhenjiang, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lulu","family":"Li","sequence":"additional","affiliation":[{"name":"Jiangsu University of Science and Technology 1 , , ,","place":["Zhenjiang, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9399-6315","authenticated-orcid":false,"given":"Fu","family":"Yang","sequence":"additional","affiliation":[{"name":"Jiangsu University of Science and Technology 1 , , ,","place":["Zhenjiang, Jiangsu, People's Republic of China"]}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"175","published-online":{"date-parts":[[2026,4,16]]},"reference":[{"key":"2026051410292173600_R1","doi-asserted-by":"crossref","first-page":"8872","DOI":"10.1021\/acscatal.1c02171","article-title":"Understanding the catalytic sites in porous hexagonal boron nitride for the epoxidation of styrene","volume":"11","author":"Fu","year":"2021","journal-title":"ACS Catal."},{"key":"2026051410292173600_R2","doi-asserted-by":"crossref","first-page":"11855","DOI":"10.1021\/acscatal.1c03164","article-title":"Investigation into enhanced catalytic performance for epoxidation of styrene over LaSrCoxFe2\u2013xO6 Double perovskites: the role of singlet oxygen species promoted by the photothermal effect","volume":"11","author":"Li","year":"2021","journal-title":"ACS Catal."},{"key":"2026051410292173600_R3","doi-asserted-by":"crossref","first-page":"121268","DOI":"10.1016\/j.apcatb.2022.121268","article-title":"Efficient photocatalytic epoxidation of styrene over a quantum-sized SnO2 on carbon nitride as a heterostructured catalyst","volume":"309","author":"Li","year":"2022","journal-title":"Appl. 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