{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T15:40:18Z","timestamp":1727710818503},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2005,10,22]],"date-time":"2005-10-22T00:00:00Z","timestamp":1129939200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2005,10,22]],"date-time":"2005-10-22T00:00:00Z","timestamp":1129939200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2005,8,5]]},"published-print":{"date-parts":[[2005,11,1]]},"abstract":"<jats:p>The title compound, [Cd(S<jats:sub>2<\/jats:sub>O<jats:sub>3<\/jats:sub>)(C<jats:sub>16<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>2<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, presents a polymeric one-dimensional structure running along the <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic> glide direction, with elementary units defined by six-coordinate Cd<jats:sup>II<\/jats:sup> atoms bonded to three symmetry-related thiosulfate groups, a bidentate tetramethylphenanthroline ligand and one aqua ligand. The bridging thiosulfates bind metal centers through two different sequences, <jats:italic>viz.<\/jats:italic> Cd\u2014S\u2014Cd\u2032 and Cd\u2032\u2014S\u2032\u2014S\u2032\u2014O\u2032\u2014Cd, defining a closed six-membered ring. Individual chains are held together <jats:italic>via<\/jats:italic> \u03c0\u2013\u03c0 interactions to generate two-dimensional networks parallel to the (100) plane. These, in turn, are connected by much weaker van der Waals interactions.<\/jats:p>","DOI":"10.1107\/s0108270105025151","type":"journal-article","created":{"date-parts":[[2005,11,4]],"date-time":"2005-11-04T16:20:35Z","timestamp":1131121235000},"page":"m494-m496","update-policy":"http:\/\/dx.doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["<i>catena<\/i>-Poly[[aqua(3,4,7,8-tetramethyl-1,10-phenanthroline-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032)cadmium(II)]-\u03bc<sub>3<\/sub>-thiosulfato-\u03ba<sup>3<\/sup>\n                  <i>S<\/i>:<i>S<\/i>:<i>O<\/i>]"],"prefix":"10.1107","volume":"61","author":[{"given":"M. Enriqueta","family":"D\u00edaz de Vivar","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergio","family":"Baggio","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mar\u00eda Teresa","family":"Garland","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ricardo","family":"Baggio","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2005,10,22]]},"container-title":["Acta Crystallographica Section C Crystal Structure Communications"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2005\/11\/00\/ob1239\/ob1239.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2005\/11\/00\/ob1239\/ob1239.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,9,30]],"date-time":"2024-09-30T14:58:17Z","timestamp":1727708297000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S0108270105025151"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,10,22]]},"references-count":0,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2005,11]]}},"alternative-id":["S0108270105025151"],"URL":"https:\/\/doi.org\/10.1107\/s0108270105025151","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S0108270105025151\/ob1239sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108270105025151\/ob1239Isup2.hkl","asserted-by":"subject"}]},"ISSN":["0108-2701"],"issn-type":[{"type":"print","value":"0108-2701"}],"subject":[],"published":{"date-parts":[[2005,10,22]]},"assertion":[{"value":"Acta Crystallographica Section C: Crystal Structure Communications","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"metal-organic compounds","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?ob1239","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"18 July 2005","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"5 August 2005","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"22 October 2005","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ob1239"}},{"value":"\u00a9 2005 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}