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The chelating benzoate ligand also bridges to the other Cu<jats:sup>2+<\/jats:sup>ion in the molecule, but the O atom involved in the bridge is different in the two complexes, being the phenolate O atom in (I) and a carboxylate O atom in (II). The bridge completes a 4+1+1 axially elongated tetragonal\u2013bipyramidal arrangement about each Cu<jats:sup>2+<\/jats:sup>cation. The complex molecules of both compounds are linked into one-dimensional supramolecular chains through O\u2014H...O hydrogen bonds.<\/jats:p>","DOI":"10.1107\/s0108270112004532","type":"journal-article","created":{"date-parts":[[2012,3,4]],"date-time":"2012-03-04T20:56:04Z","timestamp":1330894564000},"page":"m85-m89","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":7,"title":["Two centrosymmetric dinuclear phenanthroline\u2013copper(II) complexes with 3,5-dichloro-2-hydroxybenzoic acid and 5-chloro-2-hydroxybenzoic acid"],"prefix":"10.1107","volume":"68","author":[{"given":"J\u00e1n","family":"Moncol","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Klaudia","family":"Jomov\u00e1","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M\u00e1ria","family":"Porubsk\u00e1","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,2,29]]},"reference":[{"key":"sf3164_bb1","unstructured":"Agilent (2011). 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