{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T04:18:38Z","timestamp":1761970718495,"version":"build-2065373602"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2012,5,10]],"date-time":"2012-05-10T00:00:00Z","timestamp":1336608000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2012,5,10]],"date-time":"2012-05-10T00:00:00Z","timestamp":1336608000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2012,6,15]]},"abstract":"<jats:p>The molecule of 3,5-bis{4-[(benzimidazol-1-yl)methyl]phenyl}-4<jats:italic>H<\/jats:italic>-1,2,4-triazol-4-amine (<jats:italic>L<\/jats:italic>), C<jats:sub>30<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>8<\/jats:sub>, has an antiperiplanar conformation of the two terminal benzimidazole groups and forms two-dimensional networks along the crystallographic<jats:italic>b<\/jats:italic>axis<jats:italic>via<\/jats:italic>two types of intermolecular hydrogen bonds. However, in<jats:italic>catena<\/jats:italic>-poly[[[dichloridomercury(II)]-\u03bc-3,5-bis{4-[(benzimidazol-1-yl)methyl]phenyl}-4<jats:italic>H<\/jats:italic>-1,2,4-triazol-4-amine] dichloromethane hemisolvate], {[HgCl<jats:sub>2<\/jats:sub>(C<jats:sub>30<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>8<\/jats:sub>)]\u00b70.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, synthesized by the combination of<jats:italic>L<\/jats:italic>with HgCl<jats:sub>2<\/jats:sub>, the<jats:italic>L<\/jats:italic>ligand adopts a synperiplanar conformation. The Hg<jats:sup>II<\/jats:sup>cation lies in a distorted tetrahedral environment, which is defined by two N atoms and two Cl atoms to form a one-dimensional zigzag chain. These zigzag chains stack<jats:italic>via<\/jats:italic>hydrogen bonds which expand the dimensionality of the structure from one to two.<\/jats:p>","DOI":"10.1107\/s0108270112019233","type":"journal-article","created":{"date-parts":[[2012,5,9]],"date-time":"2012-05-09T16:39:02Z","timestamp":1336581542000},"page":"m152-m155","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["3,5-Bis{4-[(benzimidazol-1-yl)methyl]phenyl}-4<i>H<\/i>-1,2,4-triazol-4-amine and its one-dimensional polymeric complex with HgCl<sub>2<\/sub>"],"prefix":"10.1107","volume":"68","author":[{"given":"Yan-an","family":"Li","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qi-Kui","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Ping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu-Bin","family":"Dong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,5,10]]},"reference":[{"key":"ov3013_bb1","unstructured":"Bruker (2003). 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