{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,21]],"date-time":"2025-09-21T17:53:38Z","timestamp":1758477218854,"version":"3.32.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2012,6,13]],"date-time":"2012-06-13T00:00:00Z","timestamp":1339545600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2012,6,13]],"date-time":"2012-06-13T00:00:00Z","timestamp":1339545600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2012,7,15]]},"abstract":"<jats:p>The title compound, poly[aqua(\u03bc<jats:sub>2<\/jats:sub>-1<jats:italic>H<\/jats:italic>-imidazole-4-carboxylato-\u03ba<jats:sup>3<\/jats:sup><jats:italic>N<\/jats:italic><jats:sup>3<\/jats:sup>,<jats:italic>O<\/jats:italic>:<jats:italic>O\u2032<\/jats:italic>)hemi(\u03bc<jats:sub>2<\/jats:sub>-oxalato-\u03ba<jats:sup>4<\/jats:sup><jats:italic>O<\/jats:italic><jats:sup>1<\/jats:sup>,<jats:italic>O<\/jats:italic><jats:sup>2<\/jats:sup>:<jats:italic>O<\/jats:italic><jats:sup>1\u2032<\/jats:sup>,<jats:italic>O<\/jats:italic><jats:sup>2\u2032<\/jats:sup>)cadmium(II)], [Cd(C<jats:sub>4<\/jats:sub>H<jats:sub>3<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)(C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>)<jats:sub>0.5<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, exhibits a two-dimensional network. The Cd<jats:sup>II<\/jats:sup>cation is coordinated to one N atom and two carboxylate O atoms from two 1<jats:italic>H<\/jats:italic>-imidazole-4-carboxylate (Himc) ligands, two carboxylate O atoms from the bridging oxalate anion and one ligated water molecule; these six donor atoms form a distorted octahedral configuration. The oxalate anion lies on a centre of inversion. The Himc ligands connect the Cd<jats:sup>II<\/jats:sup>cations to form \u2013Cd\u2013Himc\u2013Cd\u2013Himc\u2013Cd\u2013 zigzag chains, with a Cd...Cd separation of 5.8206\u2005(6)\u2005\u00c5 along the<jats:italic>b<\/jats:italic>direction, which are further linked by tetradentate oxalate anions to generate a two-dimensional herringbone architecture in the<jats:italic>ab<\/jats:italic>plane. These layers are extended to form a three-dimensional supramolecular framework<jats:italic>via<\/jats:italic>O\u2014H...O and N\u2014H...O hydrogen bonds and \u03c0\u2013\u03c0 stacking interactions. The solid-state photoluminscent behaviour of the title compound has been investigated at room temperature.<\/jats:p>","DOI":"10.1107\/s0108270112023153","type":"journal-article","created":{"date-parts":[[2012,6,12]],"date-time":"2012-06-12T16:06:16Z","timestamp":1339517176000},"page":"m177-m180","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["A new two-dimensional cadmium coordination polymer with 1<i>H<\/i>-imidazole-4-carboxylate and oxalate"],"prefix":"10.1107","volume":"68","author":[{"given":"Xia","family":"Yin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Song-Liang","family":"Cai","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sheng-Run","family":"Zheng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jun","family":"Fan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei-Guang","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,6,13]]},"container-title":["Acta Crystallographica Section C Crystal Structure Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2012\/07\/00\/sf3171\/sf3171.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2012\/07\/00\/sf3171\/sf3171.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:08:46Z","timestamp":1736759326000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S0108270112023153"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,6,13]]},"references-count":0,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2012,7]]}},"alternative-id":["S0108270112023153"],"URL":"https:\/\/doi.org\/10.1107\/s0108270112023153","relation":{},"ISSN":["0108-2701"],"issn-type":[{"type":"print","value":"0108-2701"}],"subject":[],"published":{"date-parts":[[2012,6,13]]},"assertion":[{"value":"Acta Crystallographica Section C: Crystal Structure Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/c"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2011\/01\/00\/me0438\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"18 March 2012","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 May 2012","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 June 2012","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?sf3171"}},{"value":"\u00a9 2012 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}