{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T23:02:54Z","timestamp":1788822174909,"version":"build-2803163510"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2012,12,18]],"date-time":"2012-12-18T00:00:00Z","timestamp":1355788800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2012,12,18]],"date-time":"2012-12-18T00:00:00Z","timestamp":1355788800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,1,15]]},"abstract":"<jats:p>The title compound, [Sn(CH<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>16<\/jats:sub>H<jats:sub>15<\/jats:sub>NO<jats:sub>3<\/jats:sub>)], crystallized from one reaction batch with high enantiomeric excess as both a pure enantiomer and a racemate. The<jats:italic>S<\/jats:italic>enantiomer crystallizes in the chiral space group<jats:italic>P<\/jats:italic>3<jats:sub>2<\/jats:sub>. The racemate crystallizes in the space group<jats:italic>P<\/jats:italic>\\overline{1} with<jats:italic>R<\/jats:italic>and<jats:italic>S<\/jats:italic>enantiomers in the crystal lattice; these form dimers about a crystallographic inversion centre.<\/jats:p>","DOI":"10.1107\/s0108270112050470","type":"journal-article","created":{"date-parts":[[2012,12,17]],"date-time":"2012-12-17T14:06:12Z","timestamp":1355753172000},"page":"44-46","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":9,"title":["Enantiomerically pure and racemic dimethyl{<i>N<\/i>-[(2-oxidonaphthalen-1-yl-\u03ba<i>O<\/i>)methylidene]valinato-\u03ba<sup>2<\/sup><i>N<\/i>,<i>O<\/i>}tin(IV)"],"prefix":"10.1107","volume":"69","author":[{"given":"Uwe","family":"B\u00f6hme","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sabine","family":"Fels","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2012,12,18]]},"reference":[{"key":"eg3106_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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