{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:40:07Z","timestamp":1736764807627,"version":"3.32.0"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2013,2,20]],"date-time":"2013-02-20T00:00:00Z","timestamp":1361318400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,2,20]],"date-time":"2013-02-20T00:00:00Z","timestamp":1361318400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,3,15]]},"abstract":"<jats:p>In the title mixed-ligand metal\u2013organic polymeric compound, {[Cd(C<jats:sub>14<\/jats:sub>H<jats:sub>8<\/jats:sub>O<jats:sub>6<\/jats:sub>S)(C<jats:sub>16<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>2<\/jats:sub>)]\u00b73H<jats:sub>2<\/jats:sub>O}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, the asymmetric unit contains a crystallographically unique Cd<jats:sup>II<\/jats:sup>atom, one doubly deprotonated 4,4\u2032-sulfonyldibenzoic acid (H<jats:sub>2<\/jats:sub>SDBA) ligand, one 3,4,7,8-tetramethyl-1,10-phenanthroline (TMPHEN) molecule and three solvent water molecules. Each Cd<jats:sup>II<\/jats:sup>centre is six-coordinated by two O atoms from a chelating carboxylate group of a SDBA<jats:sup>2\u2212<\/jats:sup>ligand, two O atoms from monodentate carboxylate groups of two different SDBA<jats:sup>2\u2212<\/jats:sup>ligands and two N atoms from a chelating TMPHEN ligand. There are two coordination patterns for the carboxylate groups of the SDBA<jats:sup>2\u2212<\/jats:sup>ligand, with one in a \u03bc<jats:sub>1<\/jats:sub>-\u03b7<jats:sup>1<\/jats:sup>:\u03b7<jats:sup>1<\/jats:sup>chelating mode and the other in a \u03bc<jats:sub>2<\/jats:sub>-\u03b7<jats:sup>1<\/jats:sup>:\u03b7<jats:sup>1<\/jats:sup>bis-monodentate mode. Single-crystal X-ray diffraction analysis revealed that the title compound is a one-dimensional double-chain polymer containing 28-membered rings based on the [Cd<jats:sub>2<\/jats:sub>(CO<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>] rhomboid subunit. More interestingly, a chair-shaped water hexamer cluster is observed in the compound.<\/jats:p>","DOI":"10.1107\/s0108270113001352","type":"journal-article","created":{"date-parts":[[2013,2,19]],"date-time":"2013-02-19T16:10:52Z","timestamp":1361290252000},"page":"241-243","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A one-dimensional coordination polymer with a three-dimensional supramolecular framework:<i>catena<\/i>-poly[[[(3,4,7,8-tetramethyl-1,10-phenanthroline)cadmium(II)]-\u03bc<sub>3<\/sub>-4,4\u2032-sulfonyldibenzoato] trihydrate]"],"prefix":"10.1107","volume":"69","author":[{"given":"Jun","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Qing","family":"Tao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiao-Juan","family":"Xu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chun-Yun","family":"Tan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,2,20]]},"reference":[{"key":"qs3020_bb1","unstructured":"Brandenburg, K. 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