{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:13:13Z","timestamp":1736831593042,"version":"3.33.0"},"reference-count":20,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2013,2,20]],"date-time":"2013-02-20T00:00:00Z","timestamp":1361318400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,2,20]],"date-time":"2013-02-20T00:00:00Z","timestamp":1361318400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,3,15]]},"abstract":"<jats:p>In the title mixed-ligand metal\u2013organic polymeric complex [Cd(C<jats:sub>14<\/jats:sub>H<jats:sub>8<\/jats:sub>O<jats:sub>6<\/jats:sub>S)(C<jats:sub>16<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>2<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, the asymmetric unit contains a crystallographically unique Cd<jats:sup>II<\/jats:sup>atom, one doubly deprotonated 4,4\u2032-sulfonyldibenzoic acid ligand (H<jats:sub>2<\/jats:sub>SDBA), one 3,4,7,8-tetramethyl-1,10-phenanthroline (TMPHEN) molecule and one water molecule. Each Cd<jats:sup>II<\/jats:sup>centre is coordinated by two N atoms from the chelating TMPHEN ligand, three O atoms from monodentate carboxylate groups of three different SDBA<jats:sup>2\u2212<\/jats:sup>ligands and one O atom from a coordinated water molecule, giving a distorted CdN<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>octahedral geometry. Single-crystal X-ray diffraction analysis reveals that the compound is a one-dimensional double-chain polymer containing 28-membered rings based on Cd<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>clusters, with a Cd...Cd separation of 3.6889\u2005(4)\u2005\u00c5. These chains are linked by O\u2014H...O and C\u2014H...O hydrogen bonds to form a three-dimensional supramolecular framework. The framework is reinforced by \u03c0\u2013\u03c0 and C\u2014O...\u03c0 interactions.<\/jats:p>","DOI":"10.1107\/s0108270113001716","type":"journal-article","created":{"date-parts":[[2013,2,19]],"date-time":"2013-02-19T16:10:52Z","timestamp":1361290252000},"page":"244-246","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A one-dimensional coordination polymer based on Cd<sub>2<\/sub>O<sub>2<\/sub>clusters: poly[aqua(\u03bc<sub>3<\/sub>-4,4\u2032-sulfonyldibenzoato)(3,4,7,8-tetramethyl-1,10-phenanthroline-\u03ba<sup>2<\/sup><i>N<\/i>,<i>N<\/i>\u2032)cadmium(II)]"],"prefix":"10.1107","volume":"69","author":[{"given":"Jian-Qing","family":"Tao","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,2,20]]},"reference":[{"key":"wq3024_bb1","unstructured":"Brandenburg, K. (1999). DIAMOND. 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