{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:13:03Z","timestamp":1736831583346,"version":"3.33.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2013,2,9]],"date-time":"2013-02-09T00:00:00Z","timestamp":1360368000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,2,9]],"date-time":"2013-02-09T00:00:00Z","timestamp":1360368000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,3,15]]},"abstract":"<jats:p>In poly[[bis(\u03bc-4,4\u2032-bi-1<jats:italic>H<\/jats:italic>-pyrazole-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic><jats:sup>2<\/jats:sup>:<jats:italic>N<\/jats:italic><jats:sup>2\u2032<\/jats:sup>)bis(3-carboxyadamantane-1-carboxylato-\u03ba<jats:italic>O<\/jats:italic><jats:sup>1<\/jats:sup>)cobalt(II)] dihydrate], {[Co(C<jats:sub>12<\/jats:sub>H<jats:sub>15<\/jats:sub>O<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b72H<jats:sub>2<\/jats:sub>O}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (I), the Co<jats:sup>2+<\/jats:sup>cation lies on an inversion centre and the 4,4\u2032-bipyrazole (4,4\u2032-bpz) ligands are also situated across centres of inversion. In its non-isomorphous cadmium analogue, {[Cd(C<jats:sub>12<\/jats:sub>H<jats:sub>15<\/jats:sub>O<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b72H<jats:sub>2<\/jats:sub>O}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (II), the Cd<jats:sup>2+<\/jats:sup>cation lies on a twofold axis. In both compounds, the metal cations adopt an octahedral coordination, with four pyrazole N atoms in the equatorial plane [Co\u2014N = 2.156\u2005(2) and 2.162\u2005(2)\u2005\u00c5; Cd\u2014N = 2.298\u2005(2) and 2.321\u2005(2)\u2005\u00c5] and two axial carboxylate O atoms [Co\u2014O = 2.1547\u2005(18)\u2005\u00c5 and Cd\u2014O = 2.347\u2005(2)\u2005\u00c5]. In both structures, interligand hydrogen bonding [N...O = 2.682\u2005(3)\u20132.819\u2005(3)\u2005\u00c5] is essential for stabilization of the<jats:italic>M<\/jats:italic>N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>environment with its unusually high (for bulky adamantanecarboxylates) number of coordinated<jats:italic>N<\/jats:italic>-donor co-ligands. The compounds adopt two-dimensional coordination connectivities and exist as square-grid [<jats:italic>M<\/jats:italic>(4,4\u2032-bpz)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>networks accommodating monodentate carboxylate ligands. The interlayer linkage is provided by hydrogen bonds from the carboxylic acid groups<jats:italic>via<\/jats:italic>the solvent water molecules [O...O = 2.565\u2005(3) and 2.616\u2005(3)\u2005\u00c5] to the carboxylate groups in the next layer [O...O\u00a0= 2.717\u2005(3)\u20132.841\u2005(3)\u2005\u00c5], thereby extending the structures in the third dimension.<\/jats:p>","DOI":"10.1107\/s0108270113003405","type":"journal-article","created":{"date-parts":[[2013,2,8]],"date-time":"2013-02-08T11:49:39Z","timestamp":1360324179000},"page":"232-236","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Cobalt(II) and cadmium(II) square grids supported with 4,4\u2032-bipyrazole and accommodating 3-carboxyadamantane-1-carboxylate"],"prefix":"10.1107","volume":"69","author":[{"given":"Olga M.","family":"Nazarenko","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eduard B.","family":"Rusanov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander N.","family":"Chernega","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Konstantin V.","family":"Domasevitch","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,2,9]]},"reference":[{"key":"eg3109_bb1","doi-asserted-by":"crossref","first-page":"3435","DOI":"10.1002\/1521-3773(20010917)40:18<3435::AID-ANIE3435>3.0.CO;2-M","volume":"40","author":"Boldog","year":"2001","journal-title":"Angew. 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