{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,4]],"date-time":"2026-06-04T19:31:43Z","timestamp":1780601503287,"version":"3.54.1"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2013,4,9]],"date-time":"2013-04-09T00:00:00Z","timestamp":1365465600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,4,9]],"date-time":"2013-04-09T00:00:00Z","timestamp":1365465600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,5,15]]},"abstract":"<jats:p>The title complex, [Ir<jats:sub>2<\/jats:sub>(C<jats:sub>18<\/jats:sub>H<jats:sub>13<\/jats:sub>FNO<jats:sub>2<\/jats:sub>S)<jats:sub>4<\/jats:sub>Cl<jats:sub>2<\/jats:sub>]\u00b7C<jats:sub>7<\/jats:sub>H<jats:sub>8<\/jats:sub>, was crystallized from dichloromethane solution under a toluene atmosphere. It is a dimeric complex in which each of the two Ir<jats:sup>III<\/jats:sup>centres is octahedrally coordinated by two bridging chloride ligands and by two chelating cyclometalated 2-(4-benzylsulfonyl-2-fluorophenyl)pyridine ligands. The crystal structure analysis unequivocally establishes the<jats:italic>trans<\/jats:italic>disposition of the two cyclometalated ligands bound to each Ir<jats:sup>III<\/jats:sup>centre, contrary to our previous hypothesis of a<jats:italic>cis<\/jats:italic>disposition. The latter was based on the<jats:sup>1<\/jats:sup>H\u00a0NMR spectra of a series of dimeric benzylsulfonyl-functionalized dichloride-bridged iridium complexes, including the compound described in the present work [Ragni<jats:italic>et al.<\/jats:italic>(2009).<jats:italic>Chem. Eur. J.<\/jats:italic><jats:bold>15<\/jats:bold>, 136\u2013148]. The toluene solvent molecules, embedded in cavities in the crystal structure, are highly disordered and could not be modelled successfully; their contribution was removed from the refinement using the SQUEEZE routine in the program<jats:italic>PLATON<\/jats:italic>[Spek (2009).<jats:italic>Acta Cryst.<\/jats:italic>D<jats:bold>65<\/jats:bold>, 148\u2013155].<\/jats:p>","DOI":"10.1107\/s010827011300663x","type":"journal-article","created":{"date-parts":[[2013,4,10]],"date-time":"2013-04-10T14:37:01Z","timestamp":1365604621000},"page":"480-482","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":7,"title":["The correct assignment of stereochemistry in di-\u03bc-dichlorido-bis{bis[2-(5-benzylsulfonyl)-3-fluoro-2-(pyridin-2-yl)phenyl-\u03ba<sup>2<\/sup><i>N<\/i>,<i>C<\/i><sup>1<\/sup>]iridium(III)} toluene monosolvate"],"prefix":"10.1107","volume":"69","author":[{"given":"Ernesto","family":"Mesto","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fernando","family":"Scordari","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maria","family":"Lacalamita","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luisa","family":"De Cola","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roberta","family":"Ragni","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gianluca Maria","family":"Farinola","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2013,4,9]]},"reference":[{"key":"fa3306_bb1","doi-asserted-by":"crossref","first-page":"8914","DOI":"10.1039\/c0dt00414f","volume":"39","author":"Baranoff","year":"2010","journal-title":"Dalton Trans."},{"key":"fa3306_bb2","doi-asserted-by":"crossref","first-page":"1487","DOI":"10.1107\/S0021889803021800","volume":"36","author":"Betteridge","year":"2003","journal-title":"J. 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