{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,15]],"date-time":"2026-08-15T05:11:05Z","timestamp":1786770665464,"version":"build-2736575974"},"reference-count":13,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2013,6,13]],"date-time":"2013-06-13T00:00:00Z","timestamp":1371081600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,6,13]],"date-time":"2013-06-13T00:00:00Z","timestamp":1371081600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,7,15]]},"abstract":"<jats:p>A new 1,3,4-oxadiazole-containing bispyridyl ligand, namely 5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3<jats:italic>H<\/jats:italic>)-thione (<jats:italic>L<\/jats:italic>), has been used to create the novel complexes tetranitratobis{\u03bc-5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3<jats:italic>H<\/jats:italic>)-thione}zinc(II), [Zn<jats:sub>2<\/jats:sub>(NO<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>4<\/jats:sub>OS)<jats:sub>2<\/jats:sub>], (I), and<jats:italic>catena<\/jats:italic>-poly[[[dinitratocopper(II)]-bis{\u03bc-5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3<jats:italic>H<\/jats:italic>)-thione}] nitrate acetonitrile sesquisolvate dichloromethane sesquisolvate], {[Cu(NO<jats:sub>3<\/jats:sub>)(C<jats:sub>14<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>4<\/jats:sub>OS)<jats:sub>2<\/jats:sub>]NO<jats:sub>3<\/jats:sub>\u00b71.5CH<jats:sub>3<\/jats:sub>CN\u00b71.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, (II). Compound (I) presents a distorted rectangular centrosymmetric Zn<jats:sub>2<\/jats:sub><jats:italic>L<\/jats:italic><jats:sub>2<\/jats:sub>ring (dimensions 9.56 \u00d7 7.06\u2005\u00c5), where each Zn<jats:sup>II<\/jats:sup>centre lies in a {ZnN<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>} coordination environment. These binuclear zinc metallocycles are linked into a two-dimensional network through nonclassical C\u2014H...O hydrogen bonds. The resulting sheets lie parallel to the<jats:italic>ac<\/jats:italic>plane. Compound (II), which crystallizes as a nonmerohedral twin, is a coordination polymer with double chains of Cu<jats:sup>II<\/jats:sup>centres linked by bridging<jats:italic>L<\/jats:italic>ligands, propagating parallel to the crystallographic<jats:italic>a<\/jats:italic>axis. The Cu<jats:sup>II<\/jats:sup>centres adopt a distorted square-pyramidal CuN<jats:sub>4<\/jats:sub>O coordination environment with apical O atoms. The chains in (II) are interlinked<jats:italic>via<\/jats:italic>two kinds of \u03c0\u2013\u03c0 stacking interactions along [0\\overline 11]. In addition, the structure of (II) contains channels parallel to the crystallographic<jats:italic>a<\/jats:italic>direction. The guest components in these channels consist of dichloromethane and acetonitrile solvent molecules and uncoordinated nitrate anions.<\/jats:p>","DOI":"10.1107\/s0108270113012134","type":"journal-article","created":{"date-parts":[[2013,6,12]],"date-time":"2013-06-12T14:30:08Z","timestamp":1371047408000},"page":"716-720","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Zn<sup>II<\/sup>and Cu<sup>II<\/sup>complexes generated from 5-(pyridin-4-yl)-3-[2-(pyridin-4-yl)ethyl]-1,3,4-oxadiazole-2(3<i>H<\/i>)-thione"],"prefix":"10.1107","volume":"69","author":[{"given":"Hang-Ju","family":"Zhao","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian-Ping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi-Kui","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu-Bin","family":"Dong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2013,6,13]]},"reference":[{"key":"ky3029_bb1","unstructured":"Bruker (2003). SADABS, SAINT and SMART. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"ky3029_bb2","doi-asserted-by":"crossref","first-page":"6810","DOI":"10.1021\/cr200077m","volume":"111","author":"Chakrabary","year":"2011","journal-title":"Chem. Rev."},{"key":"ky3029_bb3","doi-asserted-by":"crossref","first-page":"168","DOI":"10.1107\/S0021889802000249","volume":"35","author":"Cooper","year":"2002","journal-title":"J. Appl. Cryst."},{"key":"ky3029_bb4","doi-asserted-by":"crossref","first-page":"1126","DOI":"10.1021\/cr200101d","volume":"112","author":"Cui","year":"2012","journal-title":"Chem. Rev."},{"key":"ky3029_bb5","doi-asserted-by":"crossref","first-page":"4520","DOI":"10.1021\/ja0701917","volume":"129","author":"Dong","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"ky3029_bb6","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1016\/S1293-2558(03)00041-4","volume":"5","author":"Dong","year":"2003","journal-title":"Solid State Sci."},{"key":"ky3029_bb7","doi-asserted-by":"crossref","first-page":"469","DOI":"10.1126\/science.1067208","volume":"295","author":"Eddaoudi","year":"2002","journal-title":"Science"},{"key":"ky3029_bb8","doi-asserted-by":"crossref","first-page":"4476","DOI":"10.1002\/anie.201001484","volume":"49","author":"Kim","year":"2010","journal-title":"Angew. Chem. Int. Ed."},{"key":"ky3029_bb9","doi-asserted-by":"crossref","first-page":"44","DOI":"10.1039\/B916295J","volume":"46","author":"Ma","year":"2010","journal-title":"Chem. Commun."},{"key":"ky3029_bb10","doi-asserted-by":"crossref","first-page":"4670","DOI":"10.1002\/anie.200462786","volume":"44","author":"Rowsell","year":"2005","journal-title":"Angew. Chem. Int. Ed."},{"key":"ky3029_bb11","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"ky3029_bb12","doi-asserted-by":"crossref","first-page":"251","DOI":"10.1126\/science.1124985","volume":"312","author":"Yoshizawa","year":"2006","journal-title":"Science"},{"key":"ky3029_bb13","doi-asserted-by":"crossref","first-page":"2581","DOI":"10.1021\/cg800293x","volume":"8","author":"Zhang","year":"2008","journal-title":"Cryst. Growth Des."}],"container-title":["Acta Crystallographica Section C Crystal Structure Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2013\/07\/00\/ky3029\/ky3029.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2013\/07\/00\/ky3029\/ky3029.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:10:30Z","timestamp":1736763030000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S0108270113012134"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,6,13]]},"references-count":13,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2013,7]]}},"alternative-id":["S0108270113012134"],"URL":"https:\/\/doi.org\/10.1107\/s0108270113012134","relation":{},"ISSN":["0108-2701"],"issn-type":[{"value":"0108-2701","type":"print"}],"subject":[],"published":{"date-parts":[[2013,6,13]]},"assertion":[{"value":"Acta Crystallographica Section C: Crystal Structure Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/c"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2011\/01\/00\/me0438\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"29 January 2013","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"3 May 2013","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 June 2013","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?ky3029"}},{"value":"\u00a9 2013 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}