{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,3]],"date-time":"2025-10-03T17:55:27Z","timestamp":1759514127519,"version":"3.33.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2013,6,25]],"date-time":"2013-06-25T00:00:00Z","timestamp":1372118400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,6,25]],"date-time":"2013-06-25T00:00:00Z","timestamp":1372118400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,7,15]]},"abstract":"<jats:p>The isomorphous title compounds, [Tr(S<jats:sub>4<\/jats:sub>O<jats:sub>6<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b72C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO (Tr = Cd<jats:sup>II<\/jats:sup>and Zn<jats:sup>II<\/jats:sup>), consist of metal centres to which one tetrathionate and two 4,4\u2032-dimethyl-2,2\u2032-bipyridine chelating ligands bind. The structures are completed by two symmetry-related dimethylformamide solvent molecules. Each metal-centred complex is bisected by a twofold axis running through the metal centre and halving the chelating tetrathionate dianion through the central S\u2014S bond. The ancillary symmetry-related 4,4\u2032-dimethyl-2,2\u2032-bipyridine ligands act as chelates. This results in a distorted six-coordinate geometry, with similar Tr\u2014O\/N distances but central angles differing substantially from 90 and 180\u00b0. Both ligands are basically featureless from a geometric point of view, with torsion angles in both coordinated tetrathionate groups suggesting a trend linking metal size (covalent radius) and ligand `openness'. Packing is directed by (C\u2014H)<jats:sub>aromatic<\/jats:sub>...O bridges and \u03c0\u2013\u03c0 offset stacked interactions defining chains along [001], further linked by weaker (C\u2014H)<jats:sub>methyl<\/jats:sub>...O bridges, some of them mediated by the dimethylformamide solvent molecules.<\/jats:p>","DOI":"10.1107\/s0108270113016521","type":"journal-article","created":{"date-parts":[[2013,6,24]],"date-time":"2013-06-24T15:34:30Z","timestamp":1372088070000},"page":"745-749","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Two isomorphous transition metal complexes displaying a coordinated tetrathionate unit: bis(4,4\u2032-dimethyl-2,2\u2032-bipyridine-\u03ba<sup>2<\/sup><i>N<\/i>,<i>N<\/i>\u2032)(tetrathionato-\u03ba<sup>2<\/sup><i>S<\/i>,<i>S<\/i>\u2032)cadmium(II) dimethylformamide disolvate and the zinc(II) analogue"],"prefix":"10.1107","volume":"69","author":[{"given":"Miguel Angel","family":"Harvey","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sebasti\u00e1n","family":"Suarez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fabio","family":"Doctorovich","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ricardo","family":"Baggio","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,6,25]]},"reference":[{"key":"fn3139_bb1","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1107\/S0108768102003890","volume":"58","author":"Allen","year":"2002","journal-title":"Acta Cryst. 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