{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:08:17Z","timestamp":1736831297979,"version":"3.33.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2013,8,3]],"date-time":"2013-08-03T00:00:00Z","timestamp":1375488000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,8,3]],"date-time":"2013-08-03T00:00:00Z","timestamp":1375488000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,9,15]]},"abstract":"<jats:p>The reaction of tetrapropylammonium bis(acetylacetonato)gold(I) with alkyne derivatives of the tris(pyrazolyl)methane and 1,8-naphthalimide functional groups yielded two new compounds, both bridged by the linear C[triple-bond]C\u2014Au\u2014C[triple-bond]C spacer, namely tetrapropylammonium bis{3-[2,2,2-tris(1<jats:italic>H<\/jats:italic>-pyrazol-1-yl)ethoxy]prop-1-yn-1-yl}aurate(I), (C<jats:sub>16<\/jats:sub>H<jats:sub>28<\/jats:sub>N)[Au(C<jats:sub>14<\/jats:sub>H<jats:sub>13<\/jats:sub>N<jats:sub>6<\/jats:sub>O)<jats:sub>2<\/jats:sub>], and tetrapropylammonium {\u03b7<jats:sup>2<\/jats:sup>-\u03bc-3-[2,4-dioxo-3-azatricyclo[7.3.1.0<jats:sup>5,13<\/jats:sup>]trideca-1(12),5,7,9(13),10-pentaen-3-yl]prop-1-yn-yl}bis{3-[2,4-dioxo-3-azatricyclo[7.3.1.0<jats:sup>5,13<\/jats:sup>]trideca-1(12),5,7,9(13),10-pentaen-3-yl]prop-1-yn-1-yl}digold(I) deuterochloroform disolvate, (C<jats:sub>16<\/jats:sub>H<jats:sub>28<\/jats:sub>N)[Au<jats:sub>2<\/jats:sub>(C<jats:sub>15<\/jats:sub>H<jats:sub>8<\/jats:sub>NO<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>]\u00b72CDCl<jats:sub>3<\/jats:sub>. The alkyne-functionalized scorpionate ligand [Au{C[triple-bond]CCH<jats:sub>2<\/jats:sub>OCH<jats:sub>2<\/jats:sub>C(pz)<jats:sub>3<\/jats:sub>}<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>features two potentially tridentate tris(pyrazolyl)methane donor groups oriented in a `<jats:italic>trans<\/jats:italic>' position relative to the C[triple-bond]C\u2014Au\u2014C[triple-bond]C spacer. The naphthalimide-containing compound comprises a \u03c3-bonded NI\u2014CH<jats:sub>2<\/jats:sub>\u2014C[triple-bond]C\u2014Au\u2014C[triple-bond]C\u2014CH<jats:sub>2<\/jats:sub>\u2014NI unit (NI is the naphthalimide group) \u03c0-coordinated to an NI\u2014CH<jats:sub>2<\/jats:sub>\u2014C[triple-bond]C\u2014Au neutral fragment. The crystal packing of this compound is supported by \u03c0\u2013\u03c0 stacking interactions of the NI unit, generating a three-dimensional network containing channels accommodating the tetrapropylammonium cations and deuterated chloroform solvent molecules.<\/jats:p>","DOI":"10.1107\/s0108270113016636","type":"journal-article","created":{"date-parts":[[2013,8,2]],"date-time":"2013-08-02T14:00:53Z","timestamp":1375452053000},"page":"954-958","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Tris(pyrazolyl)methane and 1,8-naphthalimide-functionalized dialkynylgold(I) anionic complexes"],"prefix":"10.1107","volume":"69","author":[{"given":"Daniel L.","family":"Reger","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mark D.","family":"Smith","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Radu F.","family":"Semeniuc","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,8,3]]},"reference":[{"key":"yp3034_bb1","first-page":"799","volume":"19","author":"Alejos","year":"1995","journal-title":"New J. 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