{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,3]],"date-time":"2026-04-03T16:22:33Z","timestamp":1775233353518,"version":"3.50.1"},"reference-count":10,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2013,7,9]],"date-time":"2013-07-09T00:00:00Z","timestamp":1373328000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,7,9]],"date-time":"2013-07-09T00:00:00Z","timestamp":1373328000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,8,15]]},"abstract":"<jats:p>The monomeric title compound, aqua(nitrato-\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic>,<jats:italic>O<\/jats:italic>\u2032)(nitrato-\u03ba<jats:italic>O<\/jats:italic>){4\u2032-[4-(pyrimidin-5-yl)phenyl]-2,2\u2032:6\u2032,2\u2032\u2032-terpyridine-\u03ba<jats:sup>3<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>N<\/jats:italic>\u2032\u2032}cadmium(II) dihydrate, [Cd(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>25<\/jats:sub>H<jats:sub>17<\/jats:sub>N<jats:sub>5<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)]\u00b72H<jats:sub>2<\/jats:sub>O, consists of a seven-coordinated Cd<jats:sup>II<\/jats:sup>centre bound to the novel 4\u2032-[4-(pyrimidin-5-yl)phenyl]-2,2\u2032:6\u2032,2\u2032\u2032-terpyridine (<jats:italic>L<\/jats:italic>1) ligand (behaving as a tridentate chelate), two nitrate anions (as chelating\u2013bidentate and monodentate ligands) and a water O atom. Both chelating groups define the base of a slightly deformed pentagonal bipyramid, while the monocoordinated ligands occupy the apices. The four heterocycles in<jats:italic>L<\/jats:italic>1 form a planar skeleton, while the central benzene ring is rotated from this planar geometry by more than 30\u00b0, probably because of packing effects. Noncovalent interactions lead to the formation of columnar arrays parallel to [100].<\/jats:p>","DOI":"10.1107\/s0108270113017356","type":"journal-article","created":{"date-parts":[[2013,7,8]],"date-time":"2013-07-08T15:55:41Z","timestamp":1373298941000},"page":"822-825","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["The supramolecular structure of a cadmium complex with the new functionalized terpyridine ligand 4\u2032-[4-(pyrimidin-5-yl)phenyl]-2,2\u2032:6\u2032,2\u2032\u2032-terpyridine (<i>L<\/i>1): aqua(<i>L<\/i>1-\u03ba<sup>3<\/sup><i>N<\/i>,<i>N<\/i>\u2032,<i>N<\/i>\u2032\u2032)(nitrato-\u03ba<sup>2<\/sup><i>O<\/i>,<i>O<\/i>\u2032)(nitrato-\u03ba<i>O<\/i>)cadmium(II) dihydrate"],"prefix":"10.1107","volume":"69","author":[{"given":"Juan","family":"Granifo","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rub\u00e9n","family":"Gavi\u00f1o","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eleonora","family":"Freire","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ricardo","family":"Baggio","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,7,9]]},"reference":[{"key":"yf3039_bb1","doi-asserted-by":"crossref","first-page":"986","DOI":"10.1039\/b807193b","volume":"10","author":"Beves","year":"2008","journal-title":"CrystEngComm"},{"key":"yf3039_bb2","doi-asserted-by":"crossref","first-page":"6858","DOI":"10.1021\/cr900053k","volume":"109","author":"Brown","year":"2009","journal-title":"Chem. 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