{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:19:31Z","timestamp":1736763571596,"version":"3.32.0"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2013,8,21]],"date-time":"2013-08-21T00:00:00Z","timestamp":1377043200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,8,21]],"date-time":"2013-08-21T00:00:00Z","timestamp":1377043200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,9,15]]},"abstract":"<jats:p>The structure of the title one-dimensional<jats:italic>ABX<\/jats:italic><jats:sub>3<\/jats:sub>-type organic\u2013inorganic hybrid complex, {(C<jats:sub>13<\/jats:sub>H<jats:sub>22<\/jats:sub>N)[CdCl<jats:sub>3<\/jats:sub>]}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, consists of benzyltriethylammonium cations and one-dimensional anionic {[CdCl<jats:sub>3<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>chains, in which the Cd<jats:sup>II<\/jats:sup>centres are in an unusual two-layer five-coordinated arrangement. The Cd<jats:sup>II<\/jats:sup>atom is pentacoordinated by four bridging and one terminal chloride ligand, forming a slightly distorted trigonal bipyramidal ClCd(\u03bc-Cl)<jats:sub>4<\/jats:sub>arrangement. The trigonal bipyramid is linked by two opposite shared faces, giving rise to a zigzag linear anionic {[CdCl<jats:sub>3<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>chain. The benzyltriethylammonium cations are located in the inter-space of the inorganic network. There are C\u2014H...Cl hydrogen bonds present and these play a crucial role in linking the organic cations and inorganic layers, and also help assemble the components into a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s010827011302221x","type":"journal-article","created":{"date-parts":[[2013,8,20]],"date-time":"2013-08-20T14:05:48Z","timestamp":1377007548000},"page":"1030-1033","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A novel pentacoordinated cadmium compound:<i>catena<\/i>-poly[benzyltriethylammonium [[chloridocadmate(II)]-di-\u03bc-chlorido]]"],"prefix":"10.1107","volume":"69","author":[{"given":"Su-Wen","family":"Sun","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lei","family":"Jin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,8,21]]},"reference":[{"key":"fn3146_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"fn3146_bb2","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1107\/S0108768187009054","volume":"44","author":"Chapuis","year":"1988","journal-title":"Acta Cryst. B"},{"key":"fn3146_bb3","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1016\/S0020-1693(99)00168-1","volume":"292","author":"Chesnut","year":"1999","journal-title":"Inorg. Chim. Acta"},{"key":"fn3146_bb4","doi-asserted-by":"crossref","first-page":"1218","DOI":"10.1107\/S010827019101452X","volume":"48","author":"Doudin","year":"1992","journal-title":"Acta Cryst. C"},{"key":"fn3146_bb5","doi-asserted-by":"crossref","first-page":"5346","DOI":"10.1021\/ja0701816","volume":"129","author":"Fu","year":"2007","journal-title":"J. Am. Chem. Soc."},{"key":"fn3146_bb6","doi-asserted-by":"crossref","first-page":"3698","DOI":"10.1143\/JPSJ.57.3698","volume":"57","author":"Gesi","year":"1988","journal-title":"J. Phys. Soc. Jpn"},{"key":"fn3146_bb7","doi-asserted-by":"crossref","first-page":"3577","DOI":"10.1039\/c0cs00226g","volume":"40","author":"Hang","year":"2011","journal-title":"Chem. Soc. Rev."},{"key":"fn3146_bb8","doi-asserted-by":"crossref","first-page":"519","DOI":"10.1039\/b314522k","volume":"5","author":"Hu","year":"2003","journal-title":"CrystEngComm"},{"key":"fn3146_bb9","doi-asserted-by":"crossref","first-page":"233","DOI":"10.1016\/S0020-1693(98)00105-4","volume":"279","author":"Huang","year":"1998","journal-title":"Inorg. Chim. Acta"},{"key":"fn3146_bb10","doi-asserted-by":"crossref","first-page":"1473","DOI":"10.1016\/j.ica.2005.10.054","volume":"359","author":"Jian","year":"2006","journal-title":"Inorg. Chim. Acta"},{"key":"fn3146_bb12","doi-asserted-by":"crossref","first-page":"3042","DOI":"10.1080\/00958972.2010.504260","volume":"63","author":"Jin","year":"2010","journal-title":"J. Coord. Chem."},{"key":"fn3146_bb13","doi-asserted-by":"crossref","first-page":"1066","DOI":"10.1039\/b105984j","author":"Laskar","year":"2002","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"fn3146_bb14","doi-asserted-by":"crossref","first-page":"778","DOI":"10.1002\/aoc.892","volume":"19","author":"Matsunaga","year":"2005","journal-title":"Appl. Organomet. Chem."},{"key":"fn3146_bb15","doi-asserted-by":"crossref","first-page":"2303","DOI":"10.1107\/S0567740872005977","volume":"28","author":"Morosin","year":"1972","journal-title":"Acta Cryst. B"},{"key":"fn3146_bb16","doi-asserted-by":"crossref","first-page":"1803","DOI":"10.1107\/S0108270190013701","volume":"47","author":"Puget","year":"1991","journal-title":"Acta Cryst. C"},{"key":"fn3146_bb17","unstructured":"Rigaku (2005). CrystalClear. Rigaku Corporation, Tokyo, Japan."},{"key":"fn3146_bb18","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1016\/S0020-1693(96)05217-6","volume":"250","author":"Rogers","year":"1996","journal-title":"Inorg. Chim. Acta"},{"key":"fn3146_bb19","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"fn3146_bb20","doi-asserted-by":"crossref","first-page":"1768","DOI":"10.1107\/S0108270189013156","volume":"46","author":"Wa\u015bkowska","year":"1990","journal-title":"Acta Cryst. C"},{"key":"fn3146_bb21","doi-asserted-by":"crossref","first-page":"7689","DOI":"10.1021\/ic060654u","volume":"45","author":"Willet","year":"2006","journal-title":"Inorg. Chem."},{"key":"fn3146_bb22","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1016\/j.inoche.2012.06.017","volume":"23","author":"Wu","year":"2012","journal-title":"Inorg. Chem. Commun."},{"key":"fn3146_bb23","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/j.inoche.2012.12.032","volume":"29","author":"Wu","year":"2013","journal-title":"Inorg. Chem. Commun."},{"key":"fn3146_bb24","doi-asserted-by":"crossref","first-page":"m203","DOI":"10.1107\/S0108270105005937","volume":"61","author":"Xia","year":"2005","journal-title":"Acta Cryst. C"},{"key":"fn3146_bb25","doi-asserted-by":"crossref","first-page":"m348","DOI":"10.1107\/S0108270110040813","volume":"66","author":"Xiao","year":"2010","journal-title":"Acta Cryst. C"},{"key":"fn3146_bb26","doi-asserted-by":"crossref","first-page":"42","DOI":"10.1021\/ja808331g","volume":"131","author":"Ye","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"fn3146_bb27","doi-asserted-by":"crossref","first-page":"10468","DOI":"10.1021\/ja803021v","volume":"130","author":"Zhang","year":"2008","journal-title":"J. Am. Chem. Soc."}],"container-title":["Acta Crystallographica Section C Crystal Structure Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2013\/09\/00\/fn3146\/fn3146.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2013\/09\/00\/fn3146\/fn3146.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:11:00Z","timestamp":1736759460000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S010827011302221X"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,8,21]]},"references-count":26,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2013,9]]}},"alternative-id":["S010827011302221X"],"URL":"https:\/\/doi.org\/10.1107\/s010827011302221x","relation":{},"ISSN":["0108-2701"],"issn-type":[{"type":"print","value":"0108-2701"}],"subject":[],"published":{"date-parts":[[2013,8,21]]},"assertion":[{"value":"Acta Crystallographica Section C: Crystal Structure Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/c"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2011\/01\/00\/me0438\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"11 July 2013","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"7 August 2013","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 August 2013","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?fn3146"}},{"value":"\u00a9 2013 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}