{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T07:00:37Z","timestamp":1760425237896,"version":"3.33.0"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2013,9,28]],"date-time":"2013-09-28T00:00:00Z","timestamp":1380326400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,9,28]],"date-time":"2013-09-28T00:00:00Z","timestamp":1380326400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,10,1]]},"abstract":"<jats:p>In the title complex, [Ag<jats:sub>2<\/jats:sub>Cd(CN)<jats:sub>4<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b7H<jats:sub>2<\/jats:sub>O or<jats:italic>cis<\/jats:italic>-[Cd{Ag(CN)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>(5,5\u2032-dmbpy)<jats:sub>2<\/jats:sub>]\u00b7H<jats:sub>2<\/jats:sub>O, where 5,5\u2032-dmbpy is 5,5\u2032-dimethyl-2,2\u2032-bipyridyl, the asymmetric unit consists of a discrete neutral [Cd{Ag(CN)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>(5,5\u2032-dmbpy)<jats:sub>2<\/jats:sub>] unit and a solvent water molecule. The Cd<jats:sup>II<\/jats:sup>cation is coordinated by two bidentate chelate 5,5\u2032-dmbpy ligands and two monodentate [Ag<jats:sup>I<\/jats:sup>(CN)<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>anions, which are in a<jats:italic>cis<\/jats:italic>arrangement around the Cd<jats:sup>II<\/jats:sup>cation, leading to an octahedral CdN<jats:sub>6<\/jats:sub>geometry. The overall structure is stabilized by a combination of intermolecular hydrogen bonding, and Ag<jats:sup>I<\/jats:sup>...Ag<jats:sup>I<\/jats:sup>and \u03c0\u2013\u03c0 interactions, forming a three-dimensional supramolecular network.<\/jats:p>","DOI":"10.1107\/s0108270113025201","type":"journal-article","created":{"date-parts":[[2013,9,27]],"date-time":"2013-09-27T16:44:21Z","timestamp":1380300261000},"page":"1136-1139","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["The heterometallic cadmium\u2013silver complex<i>cis<\/i>-bis[dicyanidoargentato(I)-\u03ba<i>N<\/i>]bis(5,5\u2032-dimethyl-2,2\u2032-bipyridyl-\u03ba<sup>2<\/sup><i>N<\/i>,<i>N<\/i>\u2032)cadmium(II) monohydrate"],"prefix":"10.1107","volume":"69","author":[{"given":"Jureepan","family":"Piromchom","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nanthawat","family":"Wannarit","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chaveng","family":"Pakawatchai","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sujittra","family":"Youngme","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,9,28]]},"reference":[{"key":"wq3049_bb1","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1007\/s10870-011-0261-x","volume":"42","author":"Ahmad","year":"2012","journal-title":"J. Chem. Crystallogr."},{"key":"wq3049_bb2","doi-asserted-by":"crossref","first-page":"117","DOI":"10.1016\/S0010-8545(98)00173-8","volume":"183","author":"Blake","year":"1999","journal-title":"Coord. Chem. Rev."},{"key":"wq3049_bb3","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1021\/j100785a001","volume":"68","author":"Bondi","year":"1964","journal-title":"J. Phys. Chem."},{"key":"wq3049_bb4","unstructured":"Bruker (2000). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"wq3049_bb5","doi-asserted-by":"crossref","first-page":"2127","DOI":"10.1039\/DT9920002127","author":"Carcelli","year":"1992","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"wq3049_bb6","doi-asserted-by":"crossref","first-page":"134","DOI":"10.1016\/S0020-1693(98)00156-X","volume":"281","author":"\u010cern\u00e1k","year":"1998","journal-title":"Inorg. Chim. Acta"},{"key":"wq3049_bb7","doi-asserted-by":"crossref","first-page":"1563","DOI":"10.1107\/S0108270194005500","volume":"50","author":"\u010cern\u00e1k","year":"1994","journal-title":"Acta Cryst. C"},{"key":"wq3049_bb8","doi-asserted-by":"crossref","first-page":"1371","DOI":"10.1016\/S0277-5387(01)00621-0","volume":"20","author":"Dasna","year":"2001","journal-title":"Polyhedron"},{"key":"wq3049_bb9","doi-asserted-by":"crossref","first-page":"873","DOI":"10.1016\/S1387-7003(03)00133-3","volume":"6","author":"Dong","year":"2003","journal-title":"Inorg. Chem. Commun."},{"key":"wq3049_bb10","doi-asserted-by":"crossref","first-page":"5370","DOI":"10.1016\/j.ejmech.2011.08.041","volume":"46","author":"Etaiw","year":"2011","journal-title":"Eur. J. Med. Chem."},{"key":"wq3049_bb11","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"wq3049_bb12","doi-asserted-by":"crossref","first-page":"3885","DOI":"10.1039\/b003010o","author":"Janiak","year":"2000","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"wq3049_bb13","doi-asserted-by":"crossref","first-page":"1098","DOI":"10.1002\/anie.198710981","volume":"26","author":"Jansen","year":"1987","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"wq3049_bb14","doi-asserted-by":"crossref","first-page":"466","DOI":"10.1107\/S0021889807067908","volume":"41","author":"Macrae","year":"2008","journal-title":"J. Appl. Cryst."},{"key":"wq3049_bb15","doi-asserted-by":"crossref","first-page":"1380","DOI":"10.1021\/ic970694l","volume":"37","author":"Omary","year":"1998","journal-title":"Inorg. Chem."},{"key":"wq3049_bb16","doi-asserted-by":"crossref","first-page":"1025","DOI":"10.1039\/B200384H","volume":"26","author":"Panja","year":"2002","journal-title":"New J. Chem."},{"key":"wq3049_bb17","doi-asserted-by":"crossref","first-page":"597","DOI":"10.1021\/cr940396v","volume":"97","author":"Pyykk\u00f6","year":"1997","journal-title":"Chem. Rev."},{"key":"wq3049_bb18","doi-asserted-by":"crossref","first-page":"1419","DOI":"10.1107\/S010827018900613X","volume":"45","author":"Range","year":"1989","journal-title":"Acta Cryst. C"},{"key":"wq3049_bb19","unstructured":"Sheldrick, G. M. (2000). SADABS. University of G\u00f6ttingen, Germany."},{"key":"wq3049_bb20","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"wq3049_bb21","doi-asserted-by":"crossref","first-page":"821","DOI":"10.1246\/cl.1994.821","author":"Soma","year":"1994","journal-title":"Chem. Lett."},{"key":"wq3049_bb22","doi-asserted-by":"crossref","first-page":"1849","DOI":"10.1021\/ic950629g","volume":"35","author":"Soma","year":"1996","journal-title":"Inorg. Chem."},{"key":"wq3049_bb23","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Cryst. D"},{"key":"wq3049_bb24","doi-asserted-by":"crossref","first-page":"2763","DOI":"10.1016\/j.ica.2004.02.008","volume":"357","author":"Tri\u0161\u010d\u00edkov\u00e1","year":"2004","journal-title":"Inorg. Chim. Acta"},{"key":"wq3049_bb25","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1007\/s11243-011-9560-5","volume":"37","author":"Wannarit","year":"2012","journal-title":"Transition Met. Chem."},{"key":"wq3049_bb26","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["Acta Crystallographica Section C Crystal Structure Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2013\/10\/00\/wq3049\/wq3049.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2013\/10\/00\/wq3049\/wq3049.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:15:02Z","timestamp":1736759702000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S0108270113025201"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,9,28]]},"references-count":26,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2013,10]]}},"alternative-id":["S0108270113025201"],"URL":"https:\/\/doi.org\/10.1107\/s0108270113025201","relation":{},"ISSN":["0108-2701"],"issn-type":[{"type":"print","value":"0108-2701"}],"subject":[],"published":{"date-parts":[[2013,9,28]]},"assertion":[{"value":"Acta Crystallographica Section C: Crystal Structure Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/c"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"1 August 2013","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"11 September 2013","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 September 2013","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wq3049"}},{"value":"\u00a9 2013 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}