{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:09:28Z","timestamp":1736831368304,"version":"3.33.0"},"reference-count":36,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2013,9,28]],"date-time":"2013-09-28T00:00:00Z","timestamp":1380326400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,9,28]],"date-time":"2013-09-28T00:00:00Z","timestamp":1380326400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,10,1]]},"abstract":"<jats:p>An infinite one-dimensional cadmium metal\u2013organic chain, namely<jats:italic>catena<\/jats:italic>-poly[aquabis(\u03bc<jats:sub>3<\/jats:sub>-2,2\u2032-{[1,2-phenylenebis(methylene)]bis(sulfanediyl)}dibenzoato)dicadmium(II)], [Cd<jats:sub>2<\/jats:sub>(C<jats:sub>22<\/jats:sub>H<jats:sub>16<\/jats:sub>O<jats:sub>4<\/jats:sub>S<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, was synthesized by solvothermal reaction of Cd(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b74H<jats:sub>2<\/jats:sub>O and 2,2\u2032-{[1,2-phenylenebis(methylene)]bis(sulfanediyl)}dibenzoic acid (H<jats:sub>2<\/jats:sub><jats:italic>L<\/jats:italic>). The Cd<jats:sup>II<\/jats:sup>centres have six-coordinate CdS<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>and CdSO<jats:sub>5<\/jats:sub>geometries. Due to the flexible \u2013CH<jats:sub>2<\/jats:sub>\u2013S\u2013 arms, the<jats:italic>L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligand adopts both<jats:italic>syn<\/jats:italic>and<jats:italic>anti<\/jats:italic>conformations. Four Cd<jats:sup>II<\/jats:sup>cations are linked by two<jats:italic>syn L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligands to form a centrosymmetric planar tetranuclear Cd<jats:sup>II<\/jats:sup>core, which is further extended through bonding to the<jats:italic>anti L<\/jats:italic><jats:sup>2\u2212<\/jats:sup>ligands to form a one-dimensional metal\u2013organic chain. Adjacent one-dimensional chains are connected by C\u2014H...\u03c0 interactions and nonclassical C\u2014H...O hydrogen bonds to form the resultant three-dimensional supramolecular framework.<\/jats:p>","DOI":"10.1107\/s0108270113025699","type":"journal-article","created":{"date-parts":[[2013,9,27]],"date-time":"2013-09-27T16:44:21Z","timestamp":1380300261000},"page":"1147-1151","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["A one-dimensional cadmium metal\u2013organic chain based on a [Cd<sub>4<\/sub>(COO)<sub>4<\/sub>] secondary building unit and a flexible dicarboxylic acid ligand"],"prefix":"10.1107","volume":"69","author":[{"given":"Yong-Kai","family":"Deng","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhi-Hao","family":"Yan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Di","family":"Sun","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,9,28]]},"reference":[{"key":"ky3038_bb1","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1107\/S0108768102003890","volume":"58","author":"Allen","year":"2002","journal-title":"Acta Cryst. 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