{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,3]],"date-time":"2025-10-03T18:09:21Z","timestamp":1759514961928,"version":"3.33.0"},"reference-count":29,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2013,11,8]],"date-time":"2013-11-08T00:00:00Z","timestamp":1383868800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,11,8]],"date-time":"2013-11-08T00:00:00Z","timestamp":1383868800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,12,1]]},"abstract":"<jats:p>The crystal structure of a tin-rich heterometallic supramolecular product, [CuSn<jats:sub>8<\/jats:sub>(C<jats:sub>5<\/jats:sub>HF<jats:sub>6<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>2<\/jats:sub>F<jats:sub>6<\/jats:sub>O<jats:sub>4<\/jats:sub>)<jats:sub>4<\/jats:sub>] or [Sn<jats:sub>4<\/jats:sub>(hfpt)<jats:sub>2<\/jats:sub>\u2013Cu(hfac)<jats:sub>2<\/jats:sub>\u2013Sn<jats:sub>4<\/jats:sub>(hfpt)<jats:sub>2<\/jats:sub>], (I), is reported (hfpt is the tetraanion of 1,1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraol and hfac is the anion of 1,1,1,5,5,5-hexafluoropentane-2,4-dione). Reaction between tin(II) tetraolate, [Sn<jats:sub>4<\/jats:sub>(hfpt)<jats:sub>2<\/jats:sub>], and copper(II) \u03b2-diketonate, [Cu(hfac)<jats:sub>2<\/jats:sub>], was utilized for the preparation of (I). The asymmetric unit consists of the whole [Sn<jats:sub>4<\/jats:sub>(hfpt)<jats:sub>2<\/jats:sub>] unit and half of a [Cu(hfac)<jats:sub>2<\/jats:sub>] unit, with the Cu atom lying on an inversion center. Intermolecular Cu...O interactions from the axial positions of copper in [Cu(hfac)<jats:sub>2<\/jats:sub>] and O atoms of the hfpt ligand in [Sn<jats:sub>4<\/jats:sub>(hfpt)<jats:sub>2<\/jats:sub>] mediate the formation of a sandwich-type structure for (I). Additional intermolecular Sn...O interactions between neighbouring [Sn<jats:sub>4<\/jats:sub>(hfpt)<jats:sub>2<\/jats:sub>] units complete a two-dimensional network.<\/jats:p>","DOI":"10.1107\/s0108270113025717","type":"journal-article","created":{"date-parts":[[2013,11,7]],"date-time":"2013-11-07T13:25:26Z","timestamp":1383830726000},"page":"1427-1430","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)tetrakis(\u03bc<sub>4<\/sub>-1,1,1,5,5,5-hexafluoropentane-2,2,4,4-tetraolato)copper(II)octatin(II): a prospective precursor for Cu-doped SnO<sub>2<\/sub>films"],"prefix":"10.1107","volume":"69","author":[{"given":"Craig M.","family":"Lieberman","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alexander S.","family":"Filatov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Volodimir D.","family":"Vreshch","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Evgeny V.","family":"Dikarev","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,11,8]]},"reference":[{"key":"fa3323_bb1","doi-asserted-by":"crossref","first-page":"335","DOI":"10.1134\/1.1187182","volume":"31","author":"Akimov","year":"1994","journal-title":"Semiconductors"},{"key":"fa3323_bb2","doi-asserted-by":"crossref","first-page":"6691","DOI":"10.1016\/j.tsf.2007.01.042","volume":"515","author":"Baker","year":"2007","journal-title":"Thin Solid Films"},{"key":"fa3323_bb3","doi-asserted-by":"crossref","first-page":"63","DOI":"10.1016\/j.molstruc.2010.12.055","volume":"990","author":"Batsanov","year":"2011","journal-title":"J. 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