{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,6,18]],"date-time":"2025-06-18T07:50:50Z","timestamp":1750233050320,"version":"3.33.0"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2013,10,12]],"date-time":"2013-10-12T00:00:00Z","timestamp":1381536000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2013,10,12]],"date-time":"2013-10-12T00:00:00Z","timestamp":1381536000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst Sect C","Acta Crystallogr C","Acta Crystallogr Sect C","Acta Crystallogr Sect C Cryst Struct Commun"],"published-print":{"date-parts":[[2013,11,15]]},"abstract":"<jats:p>In the title compound, di-\u03bc-acetato-\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic>:<jats:italic>O<\/jats:italic>;\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic>:<jats:italic>O<\/jats:italic>\u2032-bis[(6-chloro-2-{(<jats:italic>E<\/jats:italic>)-[(pyridin-2-yl)methylimino]methyl}phenolato-\u03ba<jats:sup>3<\/jats:sup><jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>O<\/jats:italic>)zinc(II)], [Zn<jats:sub>2<\/jats:sub>(C<jats:sub>13<\/jats:sub>H<jats:sub>10<\/jats:sub>ClN<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b7CHCl<jats:sub>3<\/jats:sub>, the Zn<jats:sup>II<\/jats:sup>cation adopts a five-coordinate geometry and is coordinated by two N atoms and one O atom of a tridentate 6-chloro-2-{(<jats:italic>E<\/jats:italic>)-[(pyridin-2-yl)methylimino]methyl}phenolate ligand and two O atoms of two bridging acetate groups, but their coordination geometries differ. One Zn<jats:sup>II<\/jats:sup>cation adopts a distorted trigonal bipyramidal geometry and the other a square-pyramidal geometry. The two acetate ligands bridge two Zn<jats:sup>II<\/jats:sup>cations with mono- and bidentate coordination modes. The title compound exhibits a strong emission at 460\u2005nm upon excitation at 325\u2005nm with a quantum yield of 23.1%.<\/jats:p>","DOI":"10.1107\/s0108270113027212","type":"journal-article","created":{"date-parts":[[2013,10,11]],"date-time":"2013-10-11T13:24:23Z","timestamp":1381497863000},"page":"1348-1350","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Different Zn<sup>II<\/sup>cation coordination geometries in di-\u03bc-acetato-bis{2-chloro-6-[(pyridine-2-ylmethylimino)methyl]phenol}dizinc(II) chloroform monosolvate"],"prefix":"10.1107","volume":"69","author":[{"given":"Young-Inn","family":"Kim","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jin Young","family":"Lee","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Young-Kwang","family":"Song","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sung Kwon","family":"Kang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,10,12]]},"reference":[{"key":"ov3038_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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