{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,12]],"date-time":"2025-01-12T05:14:45Z","timestamp":1736658885667,"version":"3.32.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2005,1,19]],"date-time":"2005-01-19T00:00:00Z","timestamp":1106092800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2005,1,19]],"date-time":"2005-01-19T00:00:00Z","timestamp":1106092800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr B Struct Sci","Acta Cryst B","Acta Cryst Sect B","Acta Crystallogr B","Acta Crystallogr Sect B","Acta Crystallogr Sect B Struct Sci"],"accepted":{"date-parts":[[2004,10,25]]},"published-print":{"date-parts":[[2005,2,1]]},"abstract":"<jats:p>The crystal structures of two new tetravalent terbium fluorides, CaTbF<jats:sub>6<\/jats:sub> and CdTbF<jats:sub>6<\/jats:sub>, have been determined from X-ray and neutron powder diffraction data. The title compounds exhibit an <jats:italic>anti<\/jats:italic>-KSbF<jats:sub>6<\/jats:sub> structure, the three-dimensional framework of which is built of [TbF<jats:sub>6<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> chains of edge-sharing dodecahedra further linked, by sharing corners, to isolated [<jats:italic>M<\/jats:italic>F<jats:sub>6<\/jats:sub>]<jats:sup>4\u2212<\/jats:sup> octahedra (<jats:italic>M<\/jats:italic> = Ca, Cd). The mechanism of the anionic sublattice rearrangement when going from KSbF<jats:sub>6<\/jats:sub> to CaTbF<jats:sub>6<\/jats:sub> is described and related to a simple cubic fluoride-ion packing. Comparison with the crystal structures of \u03b2-BaTbF<jats:sub>6<\/jats:sub> and other representatives of the <jats:italic>M<\/jats:italic>\n                  <jats:sup>II<\/jats:sup>\n                  <jats:italic>M<\/jats:italic>^{\\prime \\rm IV}F<jats:sub>6<\/jats:sub> family allows the singular crystal-chemical properties of some fluoroterbates to be emphasized.<\/jats:p>","DOI":"10.1107\/s0108768104026928","type":"journal-article","created":{"date-parts":[[2005,1,19]],"date-time":"2005-01-19T14:47:33Z","timestamp":1106146053000},"page":"1-10","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":8,"title":["Anti-KSbF<sub>6<\/sub> structure of CaTbF<sub>6<\/sub> and CdTbF<sub>6<\/sub>: a confirmation of the singular crystal chemistry of Tb<sup>4+<\/sup> in fluorides"],"prefix":"10.1107","volume":"61","author":[{"given":"Micha\u00ebl","family":"Josse","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marc","family":"Dubois","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Malika","family":"El-Ghozzi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jo\u00ebl","family":"Cellier","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Daniel","family":"Avignant","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2005,1,19]]},"container-title":["Acta Crystallographica Section B Structural Science"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/b\/issues\/2005\/01\/00\/av5017\/av5017.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/b\/issues\/2005\/01\/00\/av5017\/av5017.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,11]],"date-time":"2025-01-11T14:03:17Z","timestamp":1736604197000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S0108768104026928"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,1,19]]},"references-count":0,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2005,2]]}},"alternative-id":["S0108768104026928"],"URL":"https:\/\/doi.org\/10.1107\/s0108768104026928","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S0108768104026928\/av5017sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768104026928\/av5017sup2.rtv","asserted-by":"subject"}]},"ISSN":["0108-7681"],"issn-type":[{"type":"print","value":"0108-7681"}],"subject":[],"published":{"date-parts":[[2005,1,19]]},"assertion":[{"value":"Acta Crystallographica Section B: Structural Science","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/b"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/b\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?av5017","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"4 July 2004","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"25 October 2004","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 January 2005","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?av5017"}},{"value":"\u00a9 2005 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}