{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,19]],"date-time":"2025-09-19T08:41:06Z","timestamp":1758271266152,"version":"3.32.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2005,5,13]],"date-time":"2005-05-13T00:00:00Z","timestamp":1115942400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2005,5,13]],"date-time":"2005-05-13T00:00:00Z","timestamp":1115942400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr B Struct Sci","Acta Cryst B","Acta Cryst Sect B","Acta Crystallogr B","Acta Crystallogr Sect B","Acta Crystallogr Sect B Struct Sci"],"accepted":{"date-parts":[[2005,4,21]]},"published-print":{"date-parts":[[2005,6,1]]},"abstract":"<jats:p>The crystal structure of [Cd(NH<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>Ni(CN)<jats:sub>4<\/jats:sub>] has been solved and refined as an incommensurate structure in four-dimensional superspace. The Xcalibur point-detector diffractometer was used for data collection up to the third-order satellites. The structure was refined from 3496 observed reflections to a final <jats:italic>R<\/jats:italic> value of 0.0371. The modulation strongly affects all the atoms of the structure. The dominating feature of the modulation is the incommensurate alternation between octahedrally and tetrahedrally coordinated Cd atoms in the electroneutral chains [\u2014Cd(NH<jats:sub>3<\/jats:sub>)<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>\u2014NC\u2014Ni(CN)<jats:sub>2<\/jats:sub>\u2014CN\u2014]<jats:sub>\u221e<\/jats:sub> (<jats:italic>n<\/jats:italic> alternates between 2 and 4). The chain is propagated along the <jats:bold>a<\/jats:bold> axis, in which the [Cd(NH<jats:sub>3<\/jats:sub>)<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>]<jats:sup>2+<\/jats:sup> cations are linked by square [Ni(CN)<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anions. The atomic positional modulations, having mainly a transversal character in the <jats:italic>c<\/jats:italic>-direction, exhibit a switching character that can be described by the crenel and sawtooth functions. The effectively pentagonal coordinated cadmium positions were detected in the intermediate regions.<\/jats:p>","DOI":"10.1107\/s0108768105012632","type":"journal-article","created":{"date-parts":[[2005,5,24]],"date-time":"2005-05-24T14:27:38Z","timestamp":1116944858000},"page":"280-286","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":12,"title":["Modulated one-dimensional structure of [Cd(NH<sub>3<\/sub>)<sub>3<\/sub>Ni(CN)<sub>4<\/sub>]"],"prefix":"10.1107","volume":"61","author":[{"given":"V\u00e1clav","family":"Pet\u0159\u00ed\u010dek","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michal","family":"Du\u0161ek","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juraj","family":"\u010cern\u00e1k","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2005,5,13]]},"container-title":["Acta Crystallographica Section B Structural Science"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/b\/issues\/2005\/03\/00\/sn5017\/sn5017.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/b\/issues\/2005\/03\/00\/sn5017\/sn5017.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,11]],"date-time":"2025-01-11T14:15:31Z","timestamp":1736604931000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S0108768105012632"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,5,13]]},"references-count":0,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2005,6]]}},"alternative-id":["S0108768105012632"],"URL":"https:\/\/doi.org\/10.1107\/s0108768105012632","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S0108768105012632\/sn5017sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768105012632\/sn5017sup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768105012632\/sn5017sup3.pdf","asserted-by":"subject"}]},"ISSN":["0108-7681"],"issn-type":[{"type":"print","value":"0108-7681"}],"subject":[],"published":{"date-parts":[[2005,5,13]]},"assertion":[{"value":"Acta Crystallographica Section B: Structural Science","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/b"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/b\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?sn5017","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"17 March 2005","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 April 2005","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"13 May 2005","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?sn5017"}},{"value":"\u00a9 2005 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}