{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,12]],"date-time":"2025-01-12T05:17:13Z","timestamp":1736659033874,"version":"3.32.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2008,3,14]],"date-time":"2008-03-14T00:00:00Z","timestamp":1205452800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2008,3,14]],"date-time":"2008-03-14T00:00:00Z","timestamp":1205452800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr B Struct Sci","Acta Cryst B","Acta Cryst Sect B","Acta Crystallogr B","Acta Crystallogr Sect B","Acta Crystallogr Sect B Struct Sci"],"accepted":{"date-parts":[[2008,2,24]]},"published-print":{"date-parts":[[2008,4,1]]},"abstract":"<jats:p>The structures of two polymorphs, one triclinic and one monoclinic, of <jats:italic>cis<\/jats:italic>-dichlorobis(dibenzyl sulfido-\u03ba<jats:italic>S<\/jats:italic>)platinum(II), <jats:italic>cis<\/jats:italic>-PtCl<jats:sub>2<\/jats:sub>(Bz<jats:sub>2<\/jats:sub>S)<jats:sub>2<\/jats:sub>, have been determined at 295, 250, 200, 150 and 100\u2005K. In both polymorphs the complex has a structure where platinum(II) coordinates two dibenzyl sulfide molecules and two chloro ligands, forming a complex with pseudo-square-planar coordination geometry. The triclinic polymorph shows disorder at all temperatures. Both polymorphs have a packing arrangement involving centrosymmetric structural dimers. <jats:italic>cis<\/jats:italic>-PtCl<jats:sub>2<\/jats:sub>(Bz<jats:sub>2<\/jats:sub>S)<jats:sub>2<\/jats:sub> belongs to a group of complexes with the general formula Pt<jats:italic>X<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>\n                  <jats:italic>L<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>, where <jats:italic>X<\/jats:italic> is a halogen and <jats:italic>L<\/jats:italic> is a ligand with a donor atom from groups 14, 15 or 16. The distribution of structural classes among 173 <jats:italic>cis<\/jats:italic>-Pt<jats:italic>X<\/jats:italic>\n                  <jats:sub>2<\/jats:sub>\n                  <jats:italic>L<\/jats:italic>\n                  <jats:sub>2<\/jats:sub> compounds found in the Cambridge Structural Database (CSD, Version 5.28, November 2006) has been investigated. The predominant structural class [notation according to Belsky &amp; Zorkii (1977). <jats:italic>Acta Cryst.<\/jats:italic> A<jats:bold>33<\/jats:bold>, 1004\u20131006] among the <jats:italic>cis<\/jats:italic> compounds is <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic>, <jats:italic>Z<\/jats:italic> = 4\u2005(1) (73 structures, 42%), followed by P\\bar 1, <jats:italic>Z<\/jats:italic> = 2 (1) (33\u2005structures, 19%). Inversion centres combined with the screw-axis\/glide plane are the dominating packing operators (56%) followed by the inversion centre (21%). The <jats:italic>cis<\/jats:italic> and <jats:italic>trans<\/jats:italic> influence in <jats:italic>cis\/trans<\/jats:italic>-PtCl<jats:sub>2<\/jats:sub>\n                  <jats:italic>L<\/jats:italic>\n                  <jats:sub>2<\/jats:sub> compounds has been investigated using data from the CSD. The <jats:italic>cis<\/jats:italic> influence is small for donor atoms in groups 15 and 16. The <jats:italic>trans<\/jats:italic> influence is small for group 16 donor atoms and for nitrogen, but for phosphorus it is significantly greater than the other donor atoms studied.<\/jats:p>","DOI":"10.1107\/s0108768108005211","type":"journal-article","created":{"date-parts":[[2008,3,28]],"date-time":"2008-03-28T15:47:55Z","timestamp":1206719275000},"page":"187-195","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["<i>Cis<\/i>\/<i>trans<\/i> isomers of Pt<i>X<\/i>\n                  <sub>2<\/sub>\n                  <i>L<\/i>\n                  <sub>2<\/sub> (<i>X<\/i> = halogen, <i>L<\/i> = neutral ligand); the crystal structures of two polymorphs of <i>cis<\/i>-dichlorobis(dibenzyl sulfido-\u03ba<i>S<\/i>)platinum(II) in the temperature range 100\u2013295\u2005K"],"prefix":"10.1107","volume":"64","author":[{"given":"Christian","family":"Hansson","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maria","family":"Lindqvist","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"\u00c5ke","family":"Oskarsson","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2008,3,14]]},"container-title":["Acta Crystallographica Section B Structural Science"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/b\/issues\/2008\/02\/00\/ry5016\/ry5016.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/b\/issues\/2008\/02\/00\/ry5016\/ry5016.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,11]],"date-time":"2025-01-11T14:35:54Z","timestamp":1736606154000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S0108768108005211"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,3,14]]},"references-count":0,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2008,4]]}},"alternative-id":["S0108768108005211"],"URL":"https:\/\/doi.org\/10.1107\/s0108768108005211","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abtri295sup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abtri250sup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abtri200sup4.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abtri150sup5.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016tri100sup6.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abmon295sup7.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abmon250sup8.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abmon200sup9.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abmon150sup10.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S0108768108005211\/ry5016abmon100sup11.hkl","asserted-by":"subject"}]},"ISSN":["0108-7681"],"issn-type":[{"type":"print","value":"0108-7681"}],"subject":[],"published":{"date-parts":[[2008,3,14]]},"assertion":[{"value":"Acta 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