{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,12]],"date-time":"2025-01-12T05:18:25Z","timestamp":1736659105289,"version":"3.32.0"},"reference-count":9,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2008,8,16]],"date-time":"2008-08-16T00:00:00Z","timestamp":1218844800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2008,8,16]],"date-time":"2008-08-16T00:00:00Z","timestamp":1218844800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"accepted":{"date-parts":[[2008,8,11]]},"published-print":{"date-parts":[[2008,9,1]]},"abstract":"<jats:p>The dinuclear centrosymmetric title compound, [Cd<jats:sub>2<\/jats:sub>(C<jats:sub>7<\/jats:sub>H<jats:sub>14<\/jats:sub>NS<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>4<\/jats:sub>)], features a tetradentate 2-pyridinealdazine ligand that chelates two Cd centres. The coordination geometry for Cd is distorted octahedral based on a <jats:italic>cis<\/jats:italic>-N<jats:sub>2<\/jats:sub>S<jats:sub>4<\/jats:sub> donor set. In the crystal structure, molecules are connected into a supramolecular chain aligned along the <jats:italic>a<\/jats:italic> direction <jats:italic>via<\/jats:italic> C\u2014H...S and C\u2014H...\u03c0 contacts, and by \u03c0\u2013\u03c0 contacts [centroid-to-centroid distance 3.5708\u2005(15)\u2005\u00c5]. 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