{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,12]],"date-time":"2025-01-12T05:18:28Z","timestamp":1736659108440,"version":"3.32.0"},"reference-count":4,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2009,5,20]],"date-time":"2009-05-20T00:00:00Z","timestamp":1242777600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2009,5,20]],"date-time":"2009-05-20T00:00:00Z","timestamp":1242777600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2009,6,1]]},"abstract":"<jats:p>In the title complex, [CoPd<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>8<\/jats:sub>H<jats:sub>11<\/jats:sub>)Cl<jats:sub>2<\/jats:sub>(C<jats:sub>40<\/jats:sub>H<jats:sub>30<\/jats:sub>P<jats:sub>2<\/jats:sub>)]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, the Co<jats:sup>I<\/jats:sup>atom is sandwiched between the cyclopentadienyl and cyclobutadiene rings. The two diphenylphosphine substituents of the cyclobutadiene ring are situated opposite to each other and bind two Pd<jats:sup>II<\/jats:sup>atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloromethane solvent molecule (equal occupancies) and one C atom and its attached H atom of each of the allyl ligands (occupancies 0.55:0.45) are disordered.<\/jats:p>","DOI":"10.1107\/s1600536809018133","type":"journal-article","created":{"date-parts":[[2009,5,20]],"date-time":"2009-05-20T07:15:13Z","timestamp":1242803713000},"page":"m669-m669","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Bis[1,3(\u03b7<sup>3<\/sup>)-allyl][\u03bc-2(\u03b7<sup>4<\/sup>)-1,3-bis(diphenylphosphino)-2,4-diphenylcyclobuta-1,3-diene-1:3\u03ba<sup>2<\/sup><i>P<\/i>:<i>P<\/i>\u2032]dichlorido-1\u03ba<i>Cl<\/i>,3\u03ba<i>Cl<\/i>-[2(\u03b7<sup>5<\/sup>)-isopropylcyclopentadienyl]-2-cobalt(I)-1,3-dipalladium(II) dichloromethane solvate"],"prefix":"10.1107","volume":"65","author":[{"given":"Chin-Pei","family":"Chang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fung-E","family":"Hong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2009,5,20]]},"reference":[{"key":"gk2195_bb1","unstructured":"Bruker (1999). 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