{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:40Z","timestamp":1736831560171,"version":"3.33.0"},"reference-count":6,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2012,3,3]],"date-time":"2012-03-03T00:00:00Z","timestamp":1330732800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,3,3]],"date-time":"2012-03-03T00:00:00Z","timestamp":1330732800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,4,1]]},"abstract":"<jats:p>The Sn, Cl and water O atoms of the title compound, [Sn<jats:sub>2<\/jats:sub>(CH<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>Cl<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b7C<jats:sub>10<\/jats:sub>H<jats:sub>20<\/jats:sub>O<jats:sub>5<\/jats:sub>, lie on a special position of 2 site symmetry. The Sn<jats:sup>IV<\/jats:sup>atom shows<jats:italic>cis<\/jats:italic>-C<jats:sub>2<\/jats:sub>SnCl<jats:sub>2<\/jats:sub>O trigonal\u2013bipyramidal coordination [C\u2014Sn\u2014C = 157.0\u2005(1)\u00b0]; however, two [Me<jats:sub>2<\/jats:sub>SnCl<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)] units are linked by a tin\u2013chlorine bridge [Sn\u2190Cl = 3.247\u2005(1)\u2005\u00c5] across a center of inversion, generating a dinuclear species, so that the geometry is better regarded as a<jats:italic>mer<\/jats:italic>-C<jats:sub>2<\/jats:sub>SnCl<jats:sub>3<\/jats:sub>O octahedron. The crown ether interacts through O\u2014H...O hydrogen with the metal atom through the coordinated water molecules in an outer-sphere manner, generating a hydrogen-bonded chain running along [101]. The 15-crown-5 molecule is disordered over the 2\/<jats:italic>m<\/jats:italic>site.<\/jats:p>","DOI":"10.1107\/s1600536812008781","type":"journal-article","created":{"date-parts":[[2012,3,4]],"date-time":"2012-03-04T10:13:58Z","timestamp":1330856038000},"page":"m354-m354","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Di-\u03bc-chlorido-bis[aquachloridodimethyltin(IV)]\u20131,4,7,10,13-pentaoxacyclopentadecane (1\/1)"],"prefix":"10.1107","volume":"68","author":[{"given":"Mostafa M.","family":"Amini","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Seik Weng","family":"Ng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,3,3]]},"reference":[{"key":"xu5444_bb1","unstructured":"Agilent (2011). CrysAlis PRO. 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