{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:36Z","timestamp":1736831556232,"version":"3.33.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2012,3,10]],"date-time":"2012-03-10T00:00:00Z","timestamp":1331337600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,3,10]],"date-time":"2012-03-10T00:00:00Z","timestamp":1331337600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,4,1]]},"abstract":"<jats:p>In the title compound (systematic name: 7-chloro-2-methylamino-5-phenyl-3<jats:italic>H<\/jats:italic>-1,4-benzodiazepine 4-oxide dichloromethane monosolvate), C<jats:sub>16<\/jats:sub>H<jats:sub>14<\/jats:sub>ClN<jats:sub>3<\/jats:sub>O\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, the seven-membered ring adopts a boat conformation with the CH<jats:sub>2<\/jats:sub>group as the prow and the two aromatic C atoms as the stern. The dihedral angle between the benzene rings is 75.25\u2005(6)\u00b0. The crystal structure features centrosymmetric pairs of chlordiazepoxide molecules linked by pairs of N\u2014H...O hydrogen bonds, which generate<jats:italic>R<\/jats:italic><jats:sub>2<\/jats:sub><jats:sup>2<\/jats:sup>(12) loops.<\/jats:p>","DOI":"10.1107\/s1600536812009695","type":"journal-article","created":{"date-parts":[[2012,3,9]],"date-time":"2012-03-09T08:51:26Z","timestamp":1331283086000},"page":"o1011-o1011","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Chlordiazepoxide dichloromethane monosolvate"],"prefix":"10.1107","volume":"68","author":[{"given":"Andreas","family":"Fischer","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,3,10]]},"reference":[{"key":"hb6668_bb1","doi-asserted-by":"crossref","first-page":"1768","DOI":"10.1107\/S0567740882007146","volume":"38","author":"Bertolasi","year":"1982","journal-title":"Acta Cryst. 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