{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:13:19Z","timestamp":1736831599211,"version":"3.33.0"},"reference-count":25,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2012,3,10]],"date-time":"2012-03-10T00:00:00Z","timestamp":1331337600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,3,10]],"date-time":"2012-03-10T00:00:00Z","timestamp":1331337600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,4,1]]},"abstract":"<jats:p>In the title compound, [Cd(C<jats:sub>2<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>](GeF<jats:sub>6<\/jats:sub>), the Cd<jats:sup>II<\/jats:sup>atom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C\u2014C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)<jats:sub>3<\/jats:sub>]<jats:sup>2+<\/jats:sup>cations and [GeF<jats:sub>6<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>anions are connected through N\u2014H...F hydrogen bonds, forming a three-dimensional supramolecular network.<\/jats:p>","DOI":"10.1107\/s160053681200983x","type":"journal-article","created":{"date-parts":[[2012,3,9]],"date-time":"2012-03-09T08:51:26Z","timestamp":1331283086000},"page":"m396-m397","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Tris(ethylenediamine-\u03ba<sup>2<\/sup><i>N<\/i>,<i>N<\/i>\u2032)cadmium hexafluoridogermanate"],"prefix":"10.1107","volume":"68","author":[{"given":"Guo-Ming","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zeng-Xin","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pei","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,3,10]]},"reference":[{"key":"hy2520_bb1","unstructured":"Brandenburg, K. 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