{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:24Z","timestamp":1736831544345,"version":"3.33.0"},"reference-count":7,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2012,3,17]],"date-time":"2012-03-17T00:00:00Z","timestamp":1331942400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,3,17]],"date-time":"2012-03-17T00:00:00Z","timestamp":1331942400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,4,1]]},"abstract":"<jats:p>The distorted octahedral geometry about the Sn<jats:sup>IV<\/jats:sup>atom in the title compound, [Sn(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>19<\/jats:sub>N<jats:sub>4<\/jats:sub>S)Cl], is defined by the<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>,<jats:italic>S<\/jats:italic>-tridentate Schiff base ligand, two mutually<jats:italic>trans ipso<\/jats:italic>-C atoms of the Sn-bound phenyl groups, and the Cl atom which is<jats:italic>trans<\/jats:italic>to the azo N atom. The two five-membered chelate rings and pyridyl ring are almost coplanar with the dihedral angle between the outer five-membered chelate and pyridine rings being 5.39\u2005(8)\u00b0. Centrosymmetric dimers feature in the crystal packing mediated by N\u2014H...S hydrogen bonds, leading to eight-membered {...HNCS}<jats:sub>2<\/jats:sub>synthons. The dimeric aggregates are connected into a three-dimensional architecture by C\u2014H...Cl and C\u2014H...\u03c0 interactions, as well as \u03c0\u2013\u03c0 interactions occurring between centrosymmetrically related pyridine rings [centroid\u2013centroid distance = 3.6322\u2005(13)\u2005\u00c5].<\/jats:p>","DOI":"10.1107\/s1600536812010902","type":"journal-article","created":{"date-parts":[[2012,3,16]],"date-time":"2012-03-16T09:00:43Z","timestamp":1331888443000},"page":"m435-m436","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Chlorido{4-cyclohexyl-1-[1-(pyridin-2-yl-\u03ba<i>N<\/i>)ethylidene]thiosemicarbazidato-\u03ba<sup>2<\/sup><i>N<\/i><sup>1<\/sup>,<i>S<\/i>}diphenyltin(IV)"],"prefix":"10.1107","volume":"68","author":[{"given":"Md. Abu","family":"Affan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Md. Abdus","family":"Salam","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ismail","family":"Jusoh","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Seik Weng","family":"Ng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Edward R. T.","family":"Tiekink","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,3,17]]},"reference":[{"key":"zl2462_bb1","unstructured":"Agilent (2011). CrysAlis PRO. Agilent Technologies, Yarnton, England."},{"key":"zl2462_bb2","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1016\/S1472-7862(02)00030-8","volume":"1","author":"Barbour","year":"2001","journal-title":"J. Supramol. Chem."},{"key":"zl2462_bb3","unstructured":"Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"zl2462_bb4","doi-asserted-by":"crossref","first-page":"m1503","DOI":"10.1107\/S1600536810044247","volume":"66","author":"Salam","year":"2010","journal-title":"Acta Cryst. E"},{"key":"zl2462_bb5","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"zl2462_bb6","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/j.molstruc.2006.04.046","volume":"826","author":"Sousa","year":"2007","journal-title":"J. Mol. Struct."},{"key":"zl2462_bb7","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. 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