{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,12]],"date-time":"2025-01-12T05:14:29Z","timestamp":1736658869432,"version":"3.32.0"},"reference-count":7,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2012,3,24]],"date-time":"2012-03-24T00:00:00Z","timestamp":1332547200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,3,24]],"date-time":"2012-03-24T00:00:00Z","timestamp":1332547200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,4,1]]},"abstract":"<jats:p>The title compound, [Cu(NCS)<jats:sub>2<\/jats:sub>(C<jats:sub>20<\/jats:sub>H<jats:sub>21<\/jats:sub>N<jats:sub>3<\/jats:sub>)]\u00b70.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, crystallized with two independent complex molecules (<jats:italic>A<\/jats:italic>and<jats:italic>B<\/jats:italic>) in the asymmetric unit, accompanied by one dichloromethane solvent molecule. Each Cu<jats:sup>II<\/jats:sup>atom has a square-pyramidal geometry, being coordinated by five N atoms, three from the (4-methylbenzyl)bis(pyridin-2-ylmethyl)amine ligand and two from the thiocyanate ligands. In the crystal, the<jats:italic>B<\/jats:italic>molecules are linked<jats:italic>via<\/jats:italic>C\u2014H...S interactions, forming chains propagating along [100].<\/jats:p>","DOI":"10.1107\/s1600536812011476","type":"journal-article","created":{"date-parts":[[2012,3,23]],"date-time":"2012-03-23T18:38:28Z","timestamp":1332527908000},"page":"m468-m468","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["[(4-Methylbenzyl)bis(pyridin-2-ylmethyl)amine-\u03ba<sup>3<\/sup><i>N<\/i>,<i>N<\/i>\u2032,<i>N<\/i>\u2032\u2032]bis(thiocyanato-\u03ba<i>S<\/i>)copper(II) dichloromethane hemisolvate"],"prefix":"10.1107","volume":"68","author":[{"given":"Yan","family":"Qi","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yang","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zheng-Ping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qiu-Yun","family":"Chen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,3,24]]},"reference":[{"key":"su2389_bb1","doi-asserted-by":"crossref","first-page":"1115","DOI":"10.1039\/b905878h","volume":"11","author":"Basudeb","year":"2009","journal-title":"Green Chem."},{"key":"su2389_bb2","doi-asserted-by":"crossref","first-page":"4414","DOI":"10.1039\/c0dt01616k","volume":"40","author":"Chen","year":"2011","journal-title":"Dalton. 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