{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T04:01:38Z","timestamp":1761969698089,"version":"build-2065373602"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2012,5,2]],"date-time":"2012-05-02T00:00:00Z","timestamp":1335916800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,5,2]],"date-time":"2012-05-02T00:00:00Z","timestamp":1335916800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,6,1]]},"abstract":"<jats:p>The asymmetric unit of the title complex, [Sb(C<jats:sub>44<\/jats:sub>H<jats:sub>28<\/jats:sub>N<jats:sub>4<\/jats:sub>)Cl<jats:sub>2<\/jats:sub>][Sb<jats:sub>2<\/jats:sub>Cl<jats:sub>8<\/jats:sub>]<jats:sub>0.5<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, is composed of a Sb<jats:sup>V<\/jats:sup> complex cation wherein the Sb atom is hexacoordinated by four N atoms of the pyrrole rings of the tetraphenylporphyrinate (TPP) ligands and two chloride ions, a half di-\u03bc-chlorido-bis[trichloridoantimonate(III)] counter-anion and a dichloromethane solvent molecule. In the cation, the average Sb\u2014N distance is 2.066\u2005(2)\u2005\u00c5, while the Sb\u2014Cl distances are 2.3410\u2005(11) and 2.3639\u2005(12)\u2005\u00c5. The central unit of the cation, SbN<jats:sub>4<\/jats:sub>C<jats:sub>20<\/jats:sub>, is far from being planar, with deviations of atoms from the least-squares plane ranging from \u22120.110\u2005(4) to 0.124\u2005(4)\u2005\u00c5. The Sb\u2014Cl distances in the anion, which is located about an inversion center, lie in the wide range 2.3715\u2005(13)\u20132.7489\u2005(13)\u2005\u00c5, the longest distances being between the Sb and bridging Cl atoms. The crystal structure is stabilized by intermolecular C\u2014H...Cl interactions involving the cations, the anions and the solvent molecules. The solvent molecule is disordered over two orientations in a 0.901\u2005(13):0.099\u2005(13) ratio.<\/jats:p>","DOI":"10.1107\/s1600536812018351","type":"journal-article","created":{"date-parts":[[2012,5,1]],"date-time":"2012-05-01T08:32:08Z","timestamp":1335861128000},"page":"m717-m718","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Dichlorido(5,10,15,20-tetraphenylporphyrinato-\u03ba<sup>4<\/sup>\n                  <i>N<\/i>)antimony(V) hemi{di-\u03bc-chlorido-bis[trichloridoantimonate(III)]} dichloromethane monosolvate"],"prefix":"10.1107","volume":"68","author":[{"given":"Raoudha","family":"Soury","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohamed Sahah","family":"Belkhiria","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Habib","family":"Nasri","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Masood","family":"Parvez","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,5,2]]},"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/06\/00\/gk2479\/gk2479.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/06\/00\/gk2479\/gk2479.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:03:23Z","timestamp":1736762603000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536812018351"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,5,2]]},"references-count":0,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2012,6]]}},"alternative-id":["S1600536812018351"],"URL":"https:\/\/doi.org\/10.1107\/s1600536812018351","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2012,5,2]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"metal-organic compounds","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?gk2479","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"19 April 2012","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"24 April 2012","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"2 May 2012","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?gk2479"}},{"value":"\u00a9 2012 Soury et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}