{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:44:38Z","timestamp":1736844278526,"version":"3.33.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2012,5,19]],"date-time":"2012-05-19T00:00:00Z","timestamp":1337385600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,5,19]],"date-time":"2012-05-19T00:00:00Z","timestamp":1337385600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,6,1]]},"abstract":"<jats:p>The asymmetric unit of the title dichloromethane hemisolvate, C<jats:sub>24<\/jats:sub>H<jats:sub>33<\/jats:sub>N<jats:sub>5<\/jats:sub>S\u00b70.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, comprises an adamantanyl\/triazole derivative and half a CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> molecule of crystallization; the latter is disordered about a twofold axis of symmetry. The piperazine ring has a chair conformation and the two N-bound substituents occupy equatorial positions. The piperazine residue is almost normal to the triazole ring [N\u2014N\u2014C\u2014N torsion angle = \u221279.9\u2005(3)\u00b0] so that to a first approximation, the molecule has an L-shape. Linear supramolecular chains parallel to [001] are formed <jats:italic>via<\/jats:italic> C\u2014H...S interactions. Two such chains are linked into a double chain <jats:italic>via<\/jats:italic> C\u2014H...Cl interactions involving the disordered CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> molecules of solvation. <\/jats:p>","DOI":"10.1107\/s1600536812021393","type":"journal-article","created":{"date-parts":[[2012,5,18]],"date-time":"2012-05-18T08:07:56Z","timestamp":1337328476000},"page":"o1772-o1773","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["3-(Adamantan-1-yl)-4-methyl-1-[(4-phenylpiperazin-1-yl)methyl]-1<i>H<\/i>-1,2,4-triazole-5(4<i>H<\/i>)-thione dichloromethane hemisolvate"],"prefix":"10.1107","volume":"68","author":[{"given":"Ali A.","family":"El-Emam","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mohamed A.","family":"Al-Omar","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Abdul-Malek S.","family":"Al-Tamimi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Seik Weng","family":"Ng","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Edward R. T.","family":"Tiekink","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,5,19]]},"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/06\/00\/hg5226\/hg5226.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/06\/00\/hg5226\/hg5226.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:04:06Z","timestamp":1736762646000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536812021393"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,5,19]]},"references-count":0,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2012,6]]}},"alternative-id":["S1600536812021393"],"URL":"https:\/\/doi.org\/10.1107\/s1600536812021393","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2012,5,19]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"organic compounds","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?hg5226","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"10 May 2012","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"11 May 2012","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 May 2012","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?hg5226"}},{"value":"\u00a9 2012 El-Emam et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}