{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,18]],"date-time":"2025-12-18T19:39:36Z","timestamp":1766086776821,"version":"3.33.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2012,5,26]],"date-time":"2012-05-26T00:00:00Z","timestamp":1337990400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,5,26]],"date-time":"2012-05-26T00:00:00Z","timestamp":1337990400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,6,1]]},"abstract":"<jats:p>In the title compound, [CrCl<jats:sub>2<\/jats:sub>(C<jats:sub>3<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>[ZnCl<jats:sub>4<\/jats:sub>], the Cr<jats:sup>III<\/jats:sup> atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a <jats:italic>trans<\/jats:italic> arrangement, displaying a distorted octahedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup> anion lies on a -4 axis. The orientations of the two six-membered chelate rings in the complex cation are in an <jats:italic>anti<\/jats:italic> chair\u2013chair conformation with respect to each other. The Cr\u2014N bond lengths are 2.087\u2005(6) and 2.097\u2005(6)\u2005\u00c5. The Cr\u2014Cl and Zn\u2014Cl bond lengths are 2.3151\u2005(16) and 2.3255\u2005(13)\u2005\u00c5, respectively. Weak intermolecular hydrogen bonds involving the tn NH<jats:sub>2<\/jats:sub> groups as donors and chloride ligands of the anion and cation as acceptors are observed.<\/jats:p>","DOI":"10.1107\/s1600536812023355","type":"journal-article","created":{"date-parts":[[2012,5,25]],"date-time":"2012-05-25T09:26:52Z","timestamp":1337938012000},"page":"m832-m832","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Bis[<i>trans<\/i>-dichloridobis(propane-1,3-diamine-\u03ba<sup>2<\/sup>\n                  <i>N<\/i>,<i>N<\/i>\u2032)chromium(III)] tetrachloridozincate determined using synchrotron radiation"],"prefix":"10.1107","volume":"68","author":[{"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Md Abdus","family":"Subhan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,5,26]]},"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/06\/00\/nk2158\/nk2158.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/06\/00\/nk2158\/nk2158.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:07:12Z","timestamp":1736762832000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536812023355"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,5,26]]},"references-count":0,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2012,6]]}},"alternative-id":["S1600536812023355"],"URL":"https:\/\/doi.org\/10.1107\/s1600536812023355","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2012,5,26]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"metal-organic compounds","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?nk2158","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"13 April 2012","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 May 2012","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"26 May 2012","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?nk2158"}},{"value":"\u00a9 2012 Moon et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}