{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:10:18Z","timestamp":1736831418093,"version":"3.33.0"},"reference-count":7,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2012,7,28]],"date-time":"2012-07-28T00:00:00Z","timestamp":1343433600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,7,28]],"date-time":"2012-07-28T00:00:00Z","timestamp":1343433600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,8,1]]},"abstract":"<jats:p>In the centrosymmetric title compound, [CdNi<jats:sub>2<\/jats:sub>(C<jats:sub>17<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(HCOO)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b72H<jats:sub>2<\/jats:sub>O, The Ni<jats:sup>II<\/jats:sup>cation is chelated by a 2,2\u2032-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolate (salpn) anion, and further coordinated by a formate anion and a water molecule in a distorted NiN<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>octahedral geometry. The Cd<jats:sup>II<\/jats:sup>cation, located on an inversion center, is coordinated by four deprotonated hydroxy groups from two salpn anions and two carboxylate O atoms from formate anions in a distorted octahedral geometry. Both formate and salpn anions bridge the Cd and Ni cations, forming a trinuclear complex. Within the salpn anion, the benzene rings are twisted to each other at a dihedral angle of 61.46\u2005(18)\u00b0. Intermolecular O\u2014H...O hydrogen bonding is present in the crystal structure. The lattice water molecule is disorder over two positions with an occupancy ratio of 0.75:0.25.<\/jats:p>","DOI":"10.1107\/s1600536812029583","type":"journal-article","created":{"date-parts":[[2012,7,28]],"date-time":"2012-07-28T00:01:04Z","timestamp":1343433664000},"page":"m1122-m1123","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Diaquadi-\u03bc-formato-bis{\u03bc-2,2\u2032-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate"],"prefix":"10.1107","volume":"68","author":[{"given":"Jian-Feng","family":"Zhang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bo","family":"Wan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wen","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qian","family":"Shi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,7,28]]},"reference":[{"key":"xu5190_bb1","unstructured":"Bruker (2002). SADABS, SMART and SAINT. Bruker AXS Inc., Madison, Winsonsin, USA."},{"key":"xu5190_bb2","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1021\/cr00060a003","volume":"84","author":"Niederhoffer","year":"1984","journal-title":"Chem. Rev."},{"key":"xu5190_bb3","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"xu5190_bb4","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1016\/0010-8545(94)80072-3","volume":"135","author":"Tisato","year":"1994","journal-title":"Coord. Chem. Rev."},{"key":"xu5190_bb5","doi-asserted-by":"crossref","first-page":"4615","DOI":"10.1021\/ic0498081","volume":"43","author":"Wang","year":"2004","journal-title":"Inorg. Chem."},{"key":"xu5190_bb6","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1016\/S0010-8545(99)00099-5","volume":"192","author":"Yamada","year":"1999","journal-title":"Coord. Chem. Rev."},{"key":"xu5190_bb7","doi-asserted-by":"crossref","first-page":"14168","DOI":"10.1021\/ja076532y","volume":"129","author":"Zhang","year":"2007","journal-title":"J. Am. Chem. Soc."}],"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/08\/00\/xu5190\/xu5190.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2012\/08\/00\/xu5190\/xu5190.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:21:06Z","timestamp":1736760066000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536812029583"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2012,7,28]]},"references-count":7,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2012,8]]}},"alternative-id":["S1600536812029583"],"URL":"https:\/\/doi.org\/10.1107\/s1600536812029583","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2012,7,28]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"27 June 2012","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 June 2012","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 July 2012","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?xu5190"}},{"value":"\u00a9 2012 Zhanget al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}