{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:09:15Z","timestamp":1736831355935,"version":"3.33.0"},"reference-count":9,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2012,7,14]],"date-time":"2012-07-14T00:00:00Z","timestamp":1342224000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,7,14]],"date-time":"2012-07-14T00:00:00Z","timestamp":1342224000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,8,1]]},"abstract":"<jats:p>In the title compound, [Fe<jats:sub>2<\/jats:sub>(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>18<\/jats:sub>H<jats:sub>16<\/jats:sub>O)]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, the C=C bonds both adopt<jats:italic>E<\/jats:italic>conformations. In one ferrocenyl group, the five-membered rings are in a near-eclipsed conformation, whereas in the other they are mutually rotated by<jats:italic>ca<\/jats:italic>21.5\u00b0. The central cyclohexanone ring adopts a sofa conformation. In the crystal, the dichloromethane solvent moleucle forms C\u2014H...O hydrogen bonds to the organometallic molecules to generate [010] chains of alternating solvent and organometallic species.<\/jats:p>","DOI":"10.1107\/s1600536812030899","type":"journal-article","created":{"date-parts":[[2012,7,13]],"date-time":"2012-07-13T10:29:27Z","timestamp":1342175367000},"page":"m1064-m1064","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["(2<i>E<\/i>,6<i>E<\/i>)-2,6-Bis(ferrocenylmethylidene)cyclohexanone dichloromethane monosolvate"],"prefix":"10.1107","volume":"68","author":[{"given":"Shi-Jia","family":"Long","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wu","family":"Yang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yong-Hong","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,7,14]]},"reference":[{"key":"hb6805_bb1","first-page":"396","volume":"24","author":"Bai","year":"2004","journal-title":"Chin. 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