{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:10:16Z","timestamp":1736831416195,"version":"3.33.0"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2012,7,21]],"date-time":"2012-07-21T00:00:00Z","timestamp":1342828800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2012,7,21]],"date-time":"2012-07-21T00:00:00Z","timestamp":1342828800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2012,8,1]]},"abstract":"<jats:p>In the title compound, [Cd(NCS)<jats:sub>2<\/jats:sub>(C<jats:sub>7<\/jats:sub>H<jats:sub>7<\/jats:sub>N<jats:sub>5<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>], the Cd<jats:sup>II<\/jats:sup>cation lies on an inversion center and is coordinated by the N atoms of two thiocyanate anions, by N atoms of two 6-(4<jats:italic>H<\/jats:italic>-1,2,4-triazol-4-yl)pyridin-2-amine ligands and by the O atoms of two water molecules in a distorted N<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>octahedral geometry. The dihedral angle between the triazole and pyridine rings is 23.15\u2005(12)\u00b0. In the crystal, molecules are linked by N\u2014H...N and O\u2014H...S hydrogen bonds. Offset \u03c0\u2013\u03c0 stacking between parallel pyridine rings of adjacent molecules is also observed, the centroid\u2013centroid distance being 3.6319\u2005(14)\u2005\u00c5.<\/jats:p>","DOI":"10.1107\/s1600536812032473","type":"journal-article","created":{"date-parts":[[2012,7,20]],"date-time":"2012-07-20T17:47:11Z","timestamp":1342806431000},"page":"m1095-m1096","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Diaquabis(thiocyanato-\u03ba<i>N<\/i>)bis[6-(4<i>H<\/i>-1,2,4-triazol-4-yl-\u03ba<i>N<\/i><sup>1<\/sup>)pyridin-2-amine]cadmium"],"prefix":"10.1107","volume":"68","author":[{"given":"Yuan-Yuan","family":"Liu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Pan","family":"Yang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bin","family":"Ding","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2012,7,21]]},"reference":[{"key":"xu5596_bb1","unstructured":"Brandenburg, K. 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