{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,13]],"date-time":"2026-02-13T14:51:46Z","timestamp":1770994306237,"version":"3.50.1"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2013,1,31]],"date-time":"2013-01-31T00:00:00Z","timestamp":1359590400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2013,1,31]],"date-time":"2013-01-31T00:00:00Z","timestamp":1359590400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2013,2,15]]},"abstract":"<jats:p>The dinuclear molecule of the title compound, [Cu<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>18<\/jats:sub>H<jats:sub>15<\/jats:sub>P)<jats:sub>4<\/jats:sub>]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu<jats:sup>I<\/jats:sup>ions<jats:italic>via<\/jats:italic>two pairs of O atoms. Two triphenylphosphine ligands also coordinate each symmetry-related Cu<jats:sup>I<\/jats:sup>ion, resulting in a distorted tetrahedral geometry [O\u2014Cu\u2014O = 80.57\u2005(5)\u00b0 and P\u2014Cu\u2014P = 125.72\u2005(2)\u00b0]. In the crystal, there are two dichloromethane solvent molecules for each dinuclear complex.<\/jats:p>","DOI":"10.1107\/s1600536813002080","type":"journal-article","created":{"date-parts":[[2013,1,30]],"date-time":"2013-01-30T08:49:11Z","timestamp":1359535751000},"page":"m126-m126","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["\u03bc-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate"],"prefix":"10.1107","volume":"69","author":[{"given":"Andrew D.","family":"Royappa","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"James A.","family":"Golen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Arnold L.","family":"Rheingold","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"A. 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