{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:10:23Z","timestamp":1736831423992,"version":"3.33.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2013,11,13]],"date-time":"2013-11-13T00:00:00Z","timestamp":1384300800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2013,11,13]],"date-time":"2013-11-13T00:00:00Z","timestamp":1384300800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2013,12,15]]},"abstract":"<jats:p>In the title compound, [RuCl(C<jats:sub>18<\/jats:sub>H<jats:sub>15<\/jats:sub>P)(C<jats:sub>26<\/jats:sub>H<jats:sub>31<\/jats:sub>N<jats:sub>2<\/jats:sub>OP)](CF<jats:sub>3<\/jats:sub>O<jats:sub>3<\/jats:sub>S)\u00b72C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>O, the Ru<jats:sup>II<\/jats:sup>ion is coordinated in a three-legged piano stool, half-sandwich-type geometry by a chlorido ligand, a triphenylphosphine and a tethered \u03b7<jats:sup>6<\/jats:sup>-(phenyl-<jats:italic>p<\/jats:italic>-<jats:italic>O<\/jats:italic>-methoxy) \u03ba<jats:sup>1<\/jats:sup>-<jats:italic>P N<\/jats:italic>-diphenylphosphino<jats:italic>N<\/jats:italic>\u2032-diisopropyl amidine ligand charge-balanced by a trifluormethansulfonate counter-anion. The \u03b7<jats:sup>6<\/jats:sup>-coordination mode of the arene incorporated into the structure was generated<jats:italic>in situ<\/jats:italic>after addition of methyl trifluoromethanesulfonate to the neutral \u03b7<jats:sup>5<\/jats:sup>-arene tethered precursor complex [RuCl(PPh<jats:sub>3<\/jats:sub>)(\u03b7<jats:sup>5<\/jats:sup>:\u03ba<jats:sup>1<\/jats:sup>-OC<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>C(NiPr<jats:sub>2<\/jats:sub>)=N-PPh<jats:sub>2<\/jats:sub>)] in dichloromethane solution.<\/jats:p>","DOI":"10.1107\/s1600536813029450","type":"journal-article","created":{"date-parts":[[2013,11,12]],"date-time":"2013-11-12T08:54:21Z","timestamp":1384246461000},"page":"m659-m660","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Chlorido(\u03b7<sup>6<\/sup>-<i>N<\/i><sup>2<\/sup>-diphenylphosphanyl-<i>N<\/i><sup>1<\/sup>,<i>N<\/i><sup>1<\/sup>-diisopropyl-4-methoxybenzamidine-\u03ba<i>P<\/i>)(triphenylphosphane-\u03ba<i>P<\/i>)ruthenium(II) trifluoromethansulfonate acetone disolvate"],"prefix":"10.1107","volume":"69","author":[{"given":"Manel","family":"K\u00e9chaou-Perrot","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Laure","family":"Vendier","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Alain","family":"Igau","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,11,13]]},"reference":[{"key":"cq2007_bb1","doi-asserted-by":"crossref","first-page":"1396","DOI":"10.1039\/b104021a","author":"Allardyce","year":"2001","journal-title":"Chem. 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