{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:10:19Z","timestamp":1736831419319,"version":"3.33.0"},"reference-count":11,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2013,11,6]],"date-time":"2013-11-06T00:00:00Z","timestamp":1383696000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2013,11,6]],"date-time":"2013-11-06T00:00:00Z","timestamp":1383696000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2013,12,15]]},"abstract":"<jats:p>In the title compound, [Al(C<jats:sub>16<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)(C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>O)]\u00b70.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, the salen complex is monomeric and the dichlormethane solvent molecule lies on a crystallographic twofold axis. The central Al atom is fivefold coordinated and possesses a square-based pyramidal environment. The Al\u2014OAlk(<jats:sup><jats:italic>i<\/jats:italic><\/jats:sup>propyl) bond [1.7404\u2005(14)\u2005\u00c5] is much shorter than the Al\u2014OAr(salen) bond lengths [1.7974\u2005(15) and 1.8094\u2005(14)\u2005\u00c5]. The isopropyloxo group forms an intramolecular C\u2014H...N hydrogen bond. In the crystal, the complex molecules are linked by weak C\u2014H...O interactions.<\/jats:p>","DOI":"10.1107\/s1600536813029644","type":"journal-article","created":{"date-parts":[[2013,11,5]],"date-time":"2013-11-05T08:59:32Z","timestamp":1383641972000},"page":"m631-m632","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["{2,2\u2032-[Ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}(isopropanolato)aluminium dichloromethane hemisolvate"],"prefix":"10.1107","volume":"69","author":[{"given":"Kirill V.","family":"Zaitsev","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ekaterina A.","family":"Kuchuk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergey S.","family":"Karlov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Galina S.","family":"Zaitseva","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrei V.","family":"Churakov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,11,6]]},"reference":[{"key":"fk2075_bb1","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1107\/S0108768102003890","volume":"58","author":"Allen","year":"2002","journal-title":"Acta Cryst. 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