{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:10:24Z","timestamp":1736831424806,"version":"3.33.0"},"reference-count":8,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2013,11,6]],"date-time":"2013-11-06T00:00:00Z","timestamp":1383696000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2013,11,6]],"date-time":"2013-11-06T00:00:00Z","timestamp":1383696000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2013,12,15]]},"abstract":"<jats:p>In the title structure, [Ti<jats:sub>2<\/jats:sub>(C<jats:sub>16<\/jats:sub>H<jats:sub>16<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>]\u00b72CHCl<jats:sub>3<\/jats:sub>, the Ti atom is coordinated in a distorted octahedral geometry by the<jats:italic>O<\/jats:italic>,<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>\u2032,<jats:italic>O<\/jats:italic>\u2032 donor set of the salalen ligand and by two \u03bc<jats:sub>2<\/jats:sub>-oxide O atoms, which bridge two Ti(salalen) fragments into a centrosymmetric dimeric unit. In the central Ti<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>2<\/jats:sub>-O)<jats:sub>2<\/jats:sub>fragment, the metal\u2013oxygen distances are significantly different [1.7962\u2005(19) and 1.9292\u2005(19)\u2005\u00c5]. In the crystal, the chloroform molecule is anchored<jats:italic>via<\/jats:italic>an N\u2014H...Cl and a bifurcated C\u2014H...(O,O) hydrogen bond. Slipped \u03c0\u2013\u03c0 stacking [shortest C...C distance = 3.585\u2005(4)\u2005\u00c5] and C\u2014H...\u03c0 interactions contribute to the coherence of the structure.<\/jats:p>","DOI":"10.1107\/s1600536813029656","type":"journal-article","created":{"date-parts":[[2013,11,5]],"date-time":"2013-11-05T08:59:32Z","timestamp":1383641972000},"page":"m635-m636","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Di-\u03bc-oxido-bis({2,2\u2032-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate"],"prefix":"10.1107","volume":"69","author":[{"given":"Kirill V.","family":"Zaitsev","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergey S.","family":"Karlov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yulia A.","family":"Piskun","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Irina V.","family":"Vasilenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrei V.","family":"Churakov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2013,11,6]]},"reference":[{"key":"qk2062_bb1","unstructured":"Bruker (2008). 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