{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:11:23Z","timestamp":1736831483726,"version":"3.33.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2014,1,18]],"date-time":"2014-01-18T00:00:00Z","timestamp":1390003200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,1,18]],"date-time":"2014-01-18T00:00:00Z","timestamp":1390003200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,2,1]]},"abstract":"<jats:p>The solvated title compound, [Fe(C<jats:sub>44<\/jats:sub>H<jats:sub>28<\/jats:sub>N<jats:sub>4<\/jats:sub>)(C<jats:sub>4<\/jats:sub>H<jats:sub>6<\/jats:sub>N<jats:sub>2<\/jats:sub>)(C<jats:sub>7<\/jats:sub>H<jats:sub>7<\/jats:sub>NO)]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, is a porphyrin complex containing an octahedrally coordinated Fe<jats:sup>II<\/jats:sup>atom with 1-methylimidazole [Fe\u2014N = 2.0651\u2005(17)\u2005\u00c5] and<jats:italic>o<\/jats:italic>-nitrosotoluene ligands at the axial positions. The<jats:italic>o<\/jats:italic>-nitrosotoluene ligand is N-bound to iron(II) [Fe\u2014N = 1.8406\u2005(18)\u00c5 and Fe\u2014N\u2014O = 122.54\u2005(14)\u00b0]. The axial N\u2014Fe\u2014N linkage is almost linear, with a bond angle of 177.15\u2005(7)\u00b0. One phenyl group of the porphyrin ligand is disordered over two orientations in a 0.710\u2005(3):0.290\u2005(3) ratio. The dichloromethane solvent molecule was severely disordered and its contribution to the scattering was removed with the SQUEEZE routine [van der Sluis &amp; Spek (1990).<jats:italic>Acta Cryst.<\/jats:italic>A<jats:bold>46<\/jats:bold>, 194\u2013201].<\/jats:p>","DOI":"10.1107\/s160053681400083x","type":"journal-article","created":{"date-parts":[[2014,1,17]],"date-time":"2014-01-17T10:30:05Z","timestamp":1389954605000},"page":"m51-m52","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["(1-Methyl-1<i>H<\/i>-imidazole-\u03ba<i>N<\/i><sup>3<\/sup>)(1-methyl-2-nitrosobenzene-\u03ba<i>N<\/i>)(5,10,15,20-tetraphenylporphyrinato-\u03ba<sup>4<\/sup><i>N<\/i>)iron(II) dichloromethane monosolvate"],"prefix":"10.1107","volume":"70","author":[{"given":"Erwin G.","family":"Abucayon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dennis","family":"Awasabisah","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Douglas R.","family":"Powell","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"George B.","family":"Richter-Addo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,1,18]]},"reference":[{"key":"hb7178_bb1","doi-asserted-by":"crossref","first-page":"2443","DOI":"10.1016\/0022-1902(70)80535-8","volume":"32","author":"Adler","year":"1970","journal-title":"J. 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