{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:11:29Z","timestamp":1736831489818,"version":"3.33.0"},"reference-count":8,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2014,2,5]],"date-time":"2014-02-05T00:00:00Z","timestamp":1391558400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,2,5]],"date-time":"2014-02-05T00:00:00Z","timestamp":1391558400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,3,1]]},"abstract":"<jats:p>The title compound, [Ir(C<jats:sub>5<\/jats:sub>H<jats:sub>10<\/jats:sub>NO<jats:sub>2<\/jats:sub>)H(C<jats:sub>3<\/jats:sub>H<jats:sub>9<\/jats:sub>P)<jats:sub>3<\/jats:sub>]PF<jats:sub>6<\/jats:sub>\u00b70.675CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, an iridium compound with a meridional arrangement of PMe<jats:sub>3<\/jats:sub>groups,<jats:italic>O<\/jats:italic>,<jats:italic>N<\/jats:italic>-bidentate coordination of D-valine and with a hydride ligand<jats:italic>trans<\/jats:italic>to the N atom is compared with the L-valine complex reported previously. As expected, the complexes from the corresponding L and D isomers of valine crystallize in enantiomorphic space groups (<jats:italic>P<\/jats:italic>4<jats:sub>3<\/jats:sub>and<jats:italic>P<\/jats:italic>4<jats:sub>1<\/jats:sub>, respectively). In the crystal, N\u2014H...O and N\u2014H...F hydrogen bonding is observed, the N\u2014H to carbonyl oxygen hydrogen bond producing a helical motif that proceeds along the 4<jats:sub>1<\/jats:sub>screw of the<jats:italic>c<\/jats:italic>axis.<\/jats:p>","DOI":"10.1107\/s1600536814002165","type":"journal-article","created":{"date-parts":[[2014,2,4]],"date-time":"2014-02-04T09:29:03Z","timestamp":1391506143000},"page":"m82-m82","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["<i>mer<\/i>-Hydridotris(trimethylphosphane-\u03ba<i>P<\/i>)(<scp>D<\/scp>-valinato-\u03ba<sup>2<\/sup><i>N<\/i>,<i>O<\/i>)iridium hexafluoridophosphate dichloromethane 0.675-solvate"],"prefix":"10.1107","volume":"70","author":[{"given":"Joseph S.","family":"Merola","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Carla","family":"Slebodnick","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael","family":"Berg","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Melissa K.","family":"Ritchie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,2,5]]},"reference":[{"key":"pk2516_bb1","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. 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