{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,7,2]],"date-time":"2025-07-02T17:14:29Z","timestamp":1751476469254,"version":"3.33.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2014,3,15]],"date-time":"2014-03-15T00:00:00Z","timestamp":1394841600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,3,15]],"date-time":"2014-03-15T00:00:00Z","timestamp":1394841600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,4,15]]},"abstract":"<jats:p>The title compound, [Sn(C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, an unexpected side product in the reaction of di-<jats:italic>tert<\/jats:italic>-butyltin(IV) oxide with nitric acid, represents the first diorganotin(IV) oxalate to be structurally characterized. The Sn<jats:sup>IV<\/jats:sup>atom of the one-dimensional coordination polymer is located on a mirror plane and is coordinated by two chelating oxalate ions with two rather different Sn\u2014O bond lengths of 2.150\u2005(1) and 2.425\u2005(1)\u2005\u00c5, and two<jats:italic>t<\/jats:italic>-butyl groups with Sn\u2014C bond lengths of 2.186\u2005(2) and 2.190\u2005(2)\u2005\u00c5. The coordination polyhedron around the Sn<jats:sup>IV<\/jats:sup>atom is a distorted tetragonal disphenoid. The centrosymmetric oxalate ion also has an asymmetric coordination geometry, as reflected by the two slightly different C\u2014O bond lengths of 1.242\u2005(2) and 1.269\u2005(2)\u2005\u00c5. The chains of the polymer propagate along the<jats:italic>b<\/jats:italic>-axis direction. Only van der Waals interactions are observed between the chains.<\/jats:p>","DOI":"10.1107\/s160053681400539x","type":"journal-article","created":{"date-parts":[[2014,3,14]],"date-time":"2014-03-14T08:33:36Z","timestamp":1394786016000},"page":"m133-m133","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["<i>catena<\/i>-Poly[[di-<i>tert<\/i>-butyltin(IV)]-\u03bc-oxalato]"],"prefix":"10.1107","volume":"70","author":[{"given":"Martin","family":"Reichelt","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hans","family":"Reuter","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,3,15]]},"reference":[{"key":"cq2010_bb1","unstructured":"Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"cq2010_bb2","unstructured":"Bruker (2009). APEX2, SADABS and SAINT. 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