{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T15:21:24Z","timestamp":1775316084042,"version":"3.50.1"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2014,7,19]],"date-time":"2014-07-19T00:00:00Z","timestamp":1405728000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,7,19]],"date-time":"2014-07-19T00:00:00Z","timestamp":1405728000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,8,15]]},"abstract":"<jats:p>The title compound,<jats:italic>catena<\/jats:italic>-poly[[bis(methanol-\u03ba<jats:italic>O<\/jats:italic>)nickel(II)]-di-\u03bc-thiocyanato-\u03ba<jats:sup>4<\/jats:sup><jats:italic>N<\/jats:italic>:<jats:italic>S<\/jats:italic>-mercurate(II)-di-\u03bc-thiocyanato-\u03ba<jats:sup>4<\/jats:sup><jats:italic>N<\/jats:italic>:<jats:italic>S<\/jats:italic>], was obtained from a gel-growth method using tetramethoxysilane as gelling agent. The crystal structure is composed of rather regular HgS<jats:sub>4<\/jats:sub>tetrahedra (point group symmetry .2.) and<jats:italic>trans<\/jats:italic>-NiN<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>octahedra (point group symmetry 2..) that are linked through thiocyanato bridges into a three-dimensional framework. The methanol molecules coordinate<jats:italic>via<\/jats:italic>the O atom to the Ni<jats:sup>2+<\/jats:sup>cations and point into the voids of this arrangement while a weak O\u2014H...S hydrogen bond to an adjacent S atom stabilizes it.<\/jats:p>","DOI":"10.1107\/s1600536814009532","type":"journal-article","created":{"date-parts":[[2014,7,18]],"date-time":"2014-07-18T12:45:46Z","timestamp":1405687546000},"page":"48-50","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of [NiHg(SCN)<sub>4<\/sub>(CH<sub>3<\/sub>OH)<sub>2<\/sub>]<sub><i>n<\/i><\/sub>"],"prefix":"10.1107","volume":"70","author":[{"given":"Matthias","family":"Weil","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thomas","family":"H\u00e4usler","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,7,19]]},"reference":[{"key":"hb0003_bb1","doi-asserted-by":"crossref","first-page":"913","DOI":"10.1016\/0025-5408(70)90140-6","volume":"5","author":"Bergman","year":"1970","journal-title":"Mater. 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