{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,19]],"date-time":"2025-09-19T07:35:16Z","timestamp":1758267316713,"version":"3.33.0"},"reference-count":8,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2014,5,17]],"date-time":"2014-05-17T00:00:00Z","timestamp":1400284800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,5,17]],"date-time":"2014-05-17T00:00:00Z","timestamp":1400284800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,6,15]]},"abstract":"<jats:p>The title compound, [Cd<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>(C<jats:sub>18<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>O)<jats:sub>2<\/jats:sub>], was obtained from the reaction of Cd(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b74H<jats:sub>2<\/jats:sub>O with 2-phenylpyridineketon picolinoyl hydrazone and sodium chloride. Each Cd<jats:sup>2+<\/jats:sup>cation is coordinated by two N atoms and one O atom of the tridentate ligand and three chloride anions, forming a distorted CdNOCl<jats:sub>3<\/jats:sub>octahedron. Each pair of adjacent metal cations is linked by two bridging chloride ligands, resulting in a dinuclear complex unit. The molecular conformation is stabilized by intramolecular N\u2014H...N and C\u2014H...O hydrogen bonds. In the crystal, molecules are linked by nonclassical C\u2014H...O and C\u2014H...Cl hydrogen bonds into a three-dimensional network. In addition, \u03c0\u2013\u03c0 stacking interactions [centroid\u2013centroid distances = 3.777\u2005(2) and 3.631\u2005(2)\u2005\u00c5] contribute to the stabilization of the crystal packing.<\/jats:p>","DOI":"10.1107\/s1600536814010630","type":"journal-article","created":{"date-parts":[[2014,5,16]],"date-time":"2014-05-16T08:33:47Z","timestamp":1400229227000},"page":"m213-m214","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Di-\u03bc-chlorido-bis(chlorido{<i>N<\/i>\u2032-[phenyl(pyridin-2-yl-\u03ba<i>N<\/i>)methylidene]pyridine-2-carbohydrazide-\u03ba<sup>2<\/sup><i>N<\/i>\u2032,<i>O<\/i>}cadmium)"],"prefix":"10.1107","volume":"70","author":[{"given":"Mehmet","family":"Akkurt","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ali Akbar","family":"Khandar","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Muhammad Nawaz","family":"Tahir","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Farhad Akbari","family":"Afkhami","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Seyed Abolfazl Hosseini","family":"Yazdi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,5,17]]},"reference":[{"key":"rz5124_bb1","doi-asserted-by":"crossref","first-page":"m842","DOI":"10.1107\/S1600536812023185","volume":"68","author":"Akkurt","year":"2012","journal-title":"Acta Cryst. E"},{"key":"rz5124_bb2","unstructured":"Bruker (2005). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"rz5124_bb3","unstructured":"Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"rz5124_bb4","doi-asserted-by":"crossref","first-page":"41","DOI":"10.1016\/j.inoche.2004.10.019","volume":"8","author":"Chen","year":"2005","journal-title":"Inorg. Chem. Commun."},{"key":"rz5124_bb5","doi-asserted-by":"crossref","first-page":"m123","DOI":"10.1107\/S1600536810053195","volume":"67","author":"Datta","year":"2011","journal-title":"Acta Cryst. E"},{"key":"rz5124_bb6","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"rz5124_bb7","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"rz5124_bb8","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Cryst. D"}],"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/06\/00\/rz5124\/rz5124.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/06\/00\/rz5124\/rz5124.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:22:22Z","timestamp":1736760142000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536814010630"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,5,17]]},"references-count":8,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2014,6]]}},"alternative-id":["S1600536814010630"],"URL":"https:\/\/doi.org\/10.1107\/s1600536814010630","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2014,5,17]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2011\/01\/00\/me0439\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"5 May 2014","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"9 May 2014","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 May 2014","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?rz5124"}},{"value":"\u00a9 2014 Akkurtet al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}