{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:12Z","timestamp":1736831532597,"version":"3.33.0"},"reference-count":6,"publisher":"International Union of Crystallography (IUCr)","issue":"7","license":[{"start":{"date-parts":[[2014,6,11]],"date-time":"2014-06-11T00:00:00Z","timestamp":1402444800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,6,11]],"date-time":"2014-06-11T00:00:00Z","timestamp":1402444800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,7,1]]},"abstract":"<jats:p>The title compound, [RuCl<jats:sub>2<\/jats:sub>(\u03b7<jats:sup>6<\/jats:sup>-C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>22<\/jats:sub>ClP)]\u00b7CHCl<jats:sub>3<\/jats:sub>, was prepared by reaction of [RuCl<jats:sub>2<\/jats:sub>(\u03b7<jats:sup>6<\/jats:sup>-C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>)]<jats:sub>2<\/jats:sub>with chlorodicyclohexylphosphane in CHCl<jats:sub>3<\/jats:sub>at 323\u2005K under argon. The Ru<jats:sup>II<\/jats:sup>atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru\u2014P bond length of 2.3247\u2005(4)\u2005\u00c5. Both cyclohexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru<jats:sup>II<\/jats:sup>complex molecule and the chloroform solvent molecule are linked by a bifurcated C\u2014H...(Cl,Cl) hydrogen bond. Intramolecular C\u2014H...Cl hydrogen bonds are also observed.<\/jats:p>","DOI":"10.1107\/s1600536814012975","type":"journal-article","created":{"date-parts":[[2014,6,10]],"date-time":"2014-06-10T08:27:04Z","timestamp":1402388824000},"page":"m255-m255","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["(\u03b7<sup>6<\/sup>-Benzene)dichlorido(chlorodicyclohexylphosphane-\u03ba<i>P<\/i>)ruthenium(II) chloroform monosolvate"],"prefix":"10.1107","volume":"70","author":[{"given":"Saravanan","family":"Gowrisankar","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Helfried","family":"Neumann","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anke","family":"Spannenberg","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Matthias","family":"Beller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,6,11]]},"reference":[{"key":"is5363_bb1","unstructured":"Bruker (2008). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"is5363_bb2","unstructured":"Bruker (2009). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"is5363_bb3","unstructured":"Bruker (2011). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"is5363_bb5","doi-asserted-by":"crossref","first-page":"m941","DOI":"10.1107\/S1600536809027676","volume":"65","author":"Jantscher","year":"2009","journal-title":"Acta Cryst. E"},{"key":"is5363_bb6","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"is5363_bb7","doi-asserted-by":"crossref","first-page":"68","DOI":"10.1016\/S0022-328X(99)00191-6","volume":"585","author":"Torres-Lubi\u00e1n","year":"1999","journal-title":"J. Organomet. Chem."}],"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/07\/00\/is5363\/is5363.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/07\/00\/is5363\/is5363.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:45:21Z","timestamp":1736761521000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536814012975"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,6,11]]},"references-count":6,"journal-issue":{"issue":"7","published-online":{"date-parts":[[2014,7]]}},"alternative-id":["S1600536814012975"],"URL":"https:\/\/doi.org\/10.1107\/s1600536814012975","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2014,6,11]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/e"},"group":{"name":"general","label":"General"}},{"value":"metal-organic compounds","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?is5363","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"21 May 2014","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"4 June 2014","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"11 June 2014","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?is5363"}},{"value":"\u00a9 2014 Gowrisankaret al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}