{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:59Z","timestamp":1736831579584,"version":"3.33.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2014,7,19]],"date-time":"2014-07-19T00:00:00Z","timestamp":1405728000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,7,19]],"date-time":"2014-07-19T00:00:00Z","timestamp":1405728000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,8,15]]},"abstract":"<jats:p>The title compound, poly[[diaquabis[1,5-bis(pyridin-4-yl)pentane-\u03ba<jats:sup>2<\/jats:sup><jats:italic>N<\/jats:italic>:<jats:italic>N<\/jats:italic>\u2032]cadmium] bis(perchlorate) 1,5-bis(pyridin-4-yl)pentane ethanol monosolvate], [Cd(C<jats:sub>15<\/jats:sub>H<jats:sub>18<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>](ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b7C<jats:sub>15<\/jats:sub>H<jats:sub>18<\/jats:sub>N<jats:sub>2<\/jats:sub>\u00b7C<jats:sub>2<\/jats:sub>H<jats:sub>6<\/jats:sub>O, is a layered coordination polymer built up from highly squashed 4<jats:sup>4<\/jats:sup>nets in which the octahedral<jats:italic>trans<\/jats:italic>-CdO<jats:sub>2<\/jats:sub>N<jats:sub>4<\/jats:sub>nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by interlayer perchlorate ions. A free 1,5-bis(pyridin-4-yl)pentane molecule and an ethanol molecule of crystallization are also found in the intersheet region. A number of O\u2014H...O, O\u2014H...N and C\u2014H...O hydrogen bonds help to consolidate the layered structure.<\/jats:p>","DOI":"10.1107\/s1600536814014779","type":"journal-article","created":{"date-parts":[[2014,7,18]],"date-time":"2014-07-18T12:45:46Z","timestamp":1405687546000},"page":"80-83","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of a layered coordination polymer based on a 4<sup>4<\/sup>net containing Cd<sup>2+<\/sup>ions and 1,5-bis(pyridin-4-yl)pentane linkers"],"prefix":"10.1107","volume":"70","author":[{"given":"William T. A.","family":"Harrison","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M. 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