{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T18:24:34Z","timestamp":1760898274259,"version":"3.33.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2014,7,2]],"date-time":"2014-07-02T00:00:00Z","timestamp":1404259200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,7,2]],"date-time":"2014-07-02T00:00:00Z","timestamp":1404259200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,8,15]]},"abstract":"<jats:p>In the title complex, [Pd(C<jats:sub>16<\/jats:sub>H<jats:sub>16<\/jats:sub>NO<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b7CHCl<jats:sub>3<\/jats:sub>, the Pd<jats:sup>II<\/jats:sup>cation lies on an inversion center. One Cl atom of the CHCl<jats:sub>3<\/jats:sub>solvent molecule lies on a twofold axis and the C\u2014H group is disordered with equal occupancies about this axis with the other Cl atom in a general position with full occupancy. The Pd<jats:sup>II<\/jats:sup>cation is four-coordinate and adopts a square-planar geometry<jats:italic>via<\/jats:italic>coordination of the imine N and phenolic O atoms of the two bidentate Schiff base anions. The N and O atoms of these ligands are mutually<jats:italic>trans<\/jats:italic>. The plane of the benzene ring makes a dihedral angle of 73.52\u2005(10)\u00b0 with that of the methoxyphenolate ring. In the crystal, molecules of the Pd<jats:sup>II<\/jats:sup>complex are arranged into sheets parallel to the<jats:italic>ac<\/jats:italic>plane, and the chloroform solvent molecules are located in the interstitial areas between the complex molecules. Weak intermolecular C\u2014H...O and C\u2014H...\u03c0 interactions stabilize the packing.<\/jats:p>","DOI":"10.1107\/s1600536814015025","type":"journal-article","created":{"date-parts":[[2014,7,1]],"date-time":"2014-07-01T15:00:37Z","timestamp":1404226837000},"page":"m289-m290","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Bis{2-methoxy-6-[(<i>E<\/i>)-(4-methylbenzyl)iminomethyl]phenolato}palladium(II) chloroform monosolvate"],"prefix":"10.1107","volume":"70","author":[{"given":"Hadariah","family":"Bahron","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Amalina Mohd","family":"Tajuddin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wan Nazihah Wan","family":"Ibrahim","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Suchada","family":"Chantrapromma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hoong-Kun","family":"Fun","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,7,2]]},"reference":[{"key":"sj5416_bb1","doi-asserted-by":"crossref","first-page":"S1","DOI":"10.1039\/p298700000s1","volume":"2","author":"Allen","year":"1987","journal-title":"J. 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