{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:40:20Z","timestamp":1736764820824,"version":"3.32.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2014,7,19]],"date-time":"2014-07-19T00:00:00Z","timestamp":1405728000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,7,19]],"date-time":"2014-07-19T00:00:00Z","timestamp":1405728000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,8,15]]},"abstract":"<jats:p>The title compound, [Sn(C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)(C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, represents the first diorganotin(IV) oxalate hydrate to be structurally characterized. The tin(IV) atom of the one-dimensional coordination polymer is located on a twofold rotation axis and is coordinated by two chelating oxalate ligands with two slightly different Sn\u2014O bond lengths of 2.290\u2005(2) and 2.365\u2005(2)\u2005\u00c5, two symmetry-related<jats:italic>n<\/jats:italic>-propyl groups with a Sn\u2014C bond lengths of 2.127\u2005(3)\u2005\u00c5, and a water molecule with a Sn\u2014O bond length of 2.262\u2005(2)\u2005\u00c5. The coordination polyhedron around the Sn<jats:sup>IV<\/jats:sup>atom is a slightly distorted pentagonal bipyramid with a nearly linear axis between the<jats:italic>trans-<\/jats:italic>oriented<jats:italic>n<\/jats:italic>-propyl groups [C\u2014Sn\u2014C = 176.8\u2005(1)\u00b0]. The bond angles between the oxygen atoms of the equatorial plane range from 70.48\u2005(6)\u00b0 to 76.12\u2005(8)\u00b0. A one-dimensional coordination polymer results from the less asymmetric bilateral coordination of the centrosymmetric oxalate anion, internally reflected by two slightly different C\u2014O bond lengths of 1.248\u2005(3) and 1.254\u2005(3)\u2005\u00c5. The chains of the polymer propagate parallel to [001] and are held together by hydrogen bonds between water molecules and oxalate anions of neighboring chains, leading to a two-dimensional network parallel to (100).<\/jats:p>","DOI":"10.1107\/s1600536814015372","type":"journal-article","created":{"date-parts":[[2014,7,18]],"date-time":"2014-07-18T12:45:46Z","timestamp":1405687546000},"page":"87-90","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of<i>catena<\/i>-poly[[aquadi-<i>n<\/i>-propyltin(IV)]-\u03bc-oxalato]"],"prefix":"10.1107","volume":"70","author":[{"given":"Martin","family":"Reichelt","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hans","family":"Reuter","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,7,19]]},"reference":[{"key":"wm5030_bb1","doi-asserted-by":"crossref","first-page":"S1","DOI":"10.1039\/p298700000s1","volume":"2","author":"Allen","year":"1987","journal-title":"J. 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A"}],"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/08\/00\/wm5030\/wm5030.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/08\/00\/wm5030\/wm5030.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:49:51Z","timestamp":1736761791000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536814015372"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,7,19]]},"references-count":12,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2014,8]]}},"alternative-id":["S1600536814015372"],"URL":"https:\/\/doi.org\/10.1107\/s1600536814015372","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2014,7,19]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"research communications","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2011\/01\/00\/me0439\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"26 June 2014","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"1 July 2014","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"19 July 2014","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5030"}},{"value":"\u00a9 2014 Reichelt and Reuter","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}