{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:12:58Z","timestamp":1736831578119,"version":"3.33.0"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2014,7,17]],"date-time":"2014-07-17T00:00:00Z","timestamp":1405555200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2014,7,17]],"date-time":"2014-07-17T00:00:00Z","timestamp":1405555200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Struct Rep Online","Acta Crystallogr E","Acta Cryst E","Acta Cryst E Struct Rep Online","Acta Cryst Sect E","Acta Cryst Sect E Struct Rep Online","Acta Crystallogr Sect E","Acta Crystallogr Sect E Struct Rep Online"],"published-print":{"date-parts":[[2014,8,15]]},"abstract":"<jats:p>In the title compound, [CdCl<jats:sub>2<\/jats:sub>(C<jats:sub>13<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>4<\/jats:sub>S)]\u00b7CH<jats:sub>3<\/jats:sub>OH, the coordination geometry of the Cd<jats:sup>II<\/jats:sup>ion is slightly distorted square-pyramidal, as indicated by the \u03c4 index of 0.36\u2005(8). The S atom, two N atoms from the pyridyl-azomethine moiety and one of the Cl atoms comprise the basal plane, while the other Cl atom occupies the apical position. The hydrazinecarbothioamide moiety adopts an<jats:italic>E<\/jats:italic>conformation with respect to the azomethine bond. The solvate molecule in the crystal lattice plays a major role in interconnecting adjacent molecules by means of O\u2014H...Cl and N\u2014H...O hydrogen-bonding interactions. A supramolecular three-dimensional architecture is sustained in terms of further N\u2014H...Cl and C\u2014H...Cl hydrogen-bonding interactions.<\/jats:p>","DOI":"10.1107\/s1600536814015694","type":"journal-article","created":{"date-parts":[[2014,7,16]],"date-time":"2014-07-16T08:28:37Z","timestamp":1405499317000},"page":"m301-m302","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Dichlorido{(2<i>E<\/i>)-2-[phenyl(pyridin-2-yl)methylidene]hydrazinecarbothioamide}cadmium(II) methanol monosolvate"],"prefix":"10.1107","volume":"70","author":[{"given":"Ambili A.","family":"Aravindakshan","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"V.","family":"Seena","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M.","family":"Sithambaresan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M. R. Prathapachandra","family":"Kurup","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2014,7,17]]},"reference":[{"key":"fj2677_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"fj2677_bb2","unstructured":"Brandenburg, K. (2010). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"fj2677_bb3","unstructured":"Bruker (2004). SADABS, APEX2, XPREP and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"fj2677_bb4","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Cryst."},{"key":"fj2677_bb5","doi-asserted-by":"crossref","first-page":"3069","DOI":"10.1016\/j.poly.2004.09.026","volume":"23","author":"Joseph","year":"2004","journal-title":"Polyhedron"},{"key":"fj2677_bb6","doi-asserted-by":"crossref","first-page":"7824","DOI":"10.1021\/ie200487g","volume":"50","author":"Kumar","year":"2011","journal-title":"Ind. Eng. Chem. Res."},{"key":"fj2677_bb7","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/j.saa.2013.04.103","volume":"113","author":"Kumar","year":"2013","journal-title":"Spectrochim. Acta Part A"},{"key":"fj2677_bb8","doi-asserted-by":"crossref","first-page":"m346","DOI":"10.1107\/S1600536812005934","volume":"68","author":"Kunnath","year":"2012","journal-title":"Acta Cryst. E"},{"key":"fj2677_bb9","doi-asserted-by":"crossref","first-page":"1931","DOI":"10.1016\/j.poly.2005.12.023","volume":"25","author":"Philip","year":"2006","journal-title":"Polyhedron"},{"key":"fj2677_bb10","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"fj2677_bb11","doi-asserted-by":"crossref","first-page":"1250","DOI":"10.1016\/j.inoche.2004.09.021","volume":"7","author":"Sreekanth","year":"2004","journal-title":"Inorg. Chem. Commun."},{"key":"fj2677_bb12","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["Acta Crystallographica Section E Structure Reports Online"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/08\/00\/fj2677\/fj2677.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2014\/08\/00\/fj2677\/fj2677.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T09:49:33Z","timestamp":1736761773000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S1600536814015694"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2014,7,17]]},"references-count":12,"journal-issue":{"issue":"8","published-online":{"date-parts":[[2014,8]]}},"alternative-id":["S1600536814015694"],"URL":"https:\/\/doi.org\/10.1107\/s1600536814015694","relation":{},"ISSN":["1600-5368"],"issn-type":[{"type":"electronic","value":"1600-5368"}],"subject":[],"published":{"date-parts":[[2014,7,17]]},"assertion":[{"value":"Acta Crystallographica Section E: Structure Reports Online","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"metal-organic compounds","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2011\/01\/00\/me0439\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"6 June 2014","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"5 July 2014","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"17 July 2014","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?fj2677"}},{"value":"\u00a9 2014 Aravindakshanet al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}